diff --git a/air-plasma-Phelps.yaml b/air-plasma-Phelps.yaml index df3b84e..7a10d5b 100644 --- a/air-plasma-Phelps.yaml +++ b/air-plasma-Phelps.yaml @@ -14,56 +14,117 @@ units: {length: cm, quantity: molec, activation-energy: K} date: Fri, 01 Aug 2025 00:00:00 -0400 generator: lxcat2yaml + manual edits +species: +- name: Electron + composition: {E: 1} + thermo: + model: NASA7 + temperature-ranges: [200.0, 6000.0] + data: + - [2.5, 0.0, 0.0, 0.0, 0.0, -745.375, -11.7246902] + note: gas L10/92 +- name: N2 + composition: {N: 2} + thermo: + model: NASA7 + temperature-ranges: [200.0, 1000.0, 6000.0] + data: + - [3.53603521, -1.58270944e-04, -4.26984251e-07, 2.3754259e-09, -1.39708206e-12, + -1047.49645, 2.94603724] + - [2.9380297, 1.4183803e-03, -5.03281045e-07, 8.07555464e-11, -4.76064275e-15, + -917.18099, 5.95521985] + note: ATcT3E +- name: O2 + composition: {O: 2} + thermo: + model: NASA7 + temperature-ranges: [200.0, 1000.0, 6000.0] + data: + - [3.78498258, -3.02002233e-03, 9.92029171e-06, -9.77840434e-09, 3.28877702e-12, + -1064.13589, 3.64780709] + - [3.65980488, 6.59877372e-04, -1.44158172e-07, 2.14656037e-11, -1.36503784e-15, + -1216.03048, 3.42074148] + note: ATcT3E +- name: O2+ + composition: {O: 2, E: -1} + thermo: + model: NASA7 + temperature-ranges: [298.15, 1000.0, 6000.0] + data: + - [4.61017167, -6.35951952e-03, 1.42425624e-05, -1.20997923e-08, 3.70956878e-12, + 1.39742229e+05, -0.201326941] + - [3.31675922, 1.11522244e-03, -3.83492556e-07, 5.72784687e-11, -2.77648381e-15, + 1.39876823e+05, 5.44726469] + note: RUS 89 +- name: N2+ + composition: {N: 2, E: -1} + thermo: + model: NASA7 + temperature-ranges: [298.15, 1000.0, 6000.0] + data: + - [3.77540711, -2.06459157e-03, 4.75752301e-06, -3.15664228e-09, 6.70509973e-13, + 1.80481115e+05, 2.69322178] + - [3.58661363, 2.53071949e-04, 1.84778214e-07, -4.55257223e-11, 3.26818029e-15, + 1.80390994e+05, 3.09584143] + note: tpis89 +- name: O + composition: {O: 1} + thermo: + model: NASA7 + temperature-ranges: [200.0, 1000.0, 6000.0] + data: + - [3.1682671, -3.27931884e-03, 6.64306396e-06, -6.12806624e-09, 2.11265971e-12, + 2.91222592e+04, 2.05193346] + - [2.54363697, -2.73162486e-05, -4.1902952e-09, 4.95481845e-12, -4.79553694e-16, + 2.9226012e+04, 4.92229457] + note: L 1/90 +- name: O2- + composition: {O: 2, E: 1} + thermo: + model: NASA7 + temperature-ranges: [298.15, 1000.0, 6000.0] + data: + - [3.66442522, -9.28741138e-04, 6.45477082e-06, -7.7470338e-09, 2.93332662e-12, + -6870.76983, 4.35140674] + - [3.95666294, 5.98141823e-04, -2.12133905e-07, 3.63267581e-11, -2.24989228e-15, + -7062.87229, 2.2787101] + note: L 4/89 + + phases: - name: air-plasma-phelps thermo: plasma elements: [N, O, E] kinetics: gas - species: - - nasa_gas.yaml/species: [Electron, O2, N2, O2+, N2+, O, O2-] - state: {T: 300.0, P: 1 atm, X: {O2: 0.21, N2: 0.79}} + species: [N2, N2+, O2, O, O2-, O2+, Electron] electron-energy-distribution: type: Boltzmann-two-term - energy-levels: [0.0, 1.0, 2.0, 3.0, 4.0, 5.0, 6.0, 7.0, 8.0, 9.0, - 10.0, 11.0, 12.0, 13.0, 14.0, 15.0, 16.0, 17.0, - 18.0, 19.0, 20.0, 21.0, 22.0, 23.0, 24.0, 25.0, - 26.0, 27.0, 28.0, 29.0, 30.0, 31.0, 32.0, 33.0, - 34.0, 35.0, 36.0, 37.0, 38.0, 39.0, 40.0] + initial_max_energy_level: 60.0 + initial_number_of_energy_grid_cells: 501 + energy_levels_distribution: Linear + energy_grid_adaptation: + enabled: true + min_decay_decades: 10.0 + max_decay_decades: 11.0 + update_factor: 0.1 + max_iterations: 1000 reactions: - equation: O2 + Electron => Electron + Electron + O2+ type: electron-collision-plasma - energy-levels: [12.06, 13.0, 18.0, 28.0, 38.0, 48.0, 58.0, 68.0, 78.0, 88.0, 100.0, - 150.0, 200.0, 300.0, 500.0, 700.0, 1000.0, 1500.0, 2000.0, 3000.0, 5000.0, 7000.0, - 10000.0] - cross-sections: [0.0, 2.3e-22, 2e-21, 7.4e-21, 1.32e-20, 1.8e-20, 2.1e-20, 2.33e-20, - 2.5e-20, 2.6e-20, 2.7e-20, 2.7e-20, 2.5e-20, 2.17e-20, 1.66e-20, 1.35e-20, 1.04e-20, - 7.6e-21, 6e-21, 4.2e-21, 2.7e-21, 2e-21, 1.4e-21] - threshold: 12.06 + collision: phelps_O2_excitation_O2^+_12.06 + - equation: O2 + Electron => O2- type: electron-collision-plasma - energy-levels: [0.0, 0.058, 0.073, 0.083, 0.089, 0.095, 0.103, 0.109, 0.15, 0.17, 0.2, - 0.21, 0.23, 0.32, 0.33, 0.35, 0.44, 0.45, 0.47, 0.56, 0.57, 0.59, 0.68, 0.69, 0.71, - 0.79, 0.8, 0.82, 0.9, 0.91, 0.93, 1.02, 1.03, 1.05, 1.5, 10000.0] - cross-sections: [0.0, 0.0, 5.60795e-41, 1.80256e-40, 4.20596e-41, 8.41193e-41, - 1.80256e-40, 0.0, 0.0, 0.0, 0.0, 3.56506e-41, 0.0, 0.0, 2.30327e-41, 0.0, 0.0, - 1.45206e-41, 0.0, 0.0, 1.10156e-41, 0.0, 0.0, 8.01136e-42, 0.0, 0.0, 7.00994e-42, - 0.0, 0.0, 5.50781e-42, 0.0, 0.0, 4.20596e-42, 0.0, 0.0, 0.0] - threshold: 0.0 - rate-constant: {A: 6.0e-5, b: 0.0, Ea_gas: 0.0, be: -1.0, Ea_electron: 0.0} + collision: phelps_O2_attachement_O2^-_0.0 + - equation: N2 + Electron => N2+ + 2 Electron type: electron-collision-plasma - energy-levels: [0.0, 15.6, 16.0, 16.5, 17.0, 17.5, 18.0, 18.5, 19.0, 19.5, 20.0, 21.0, - 22.0, 23.0, 25.0, 30.0, 34.0, 45.0, 60.0, 75.0, 100.0, 150.0, 200.0, 300.0, 500.0, - 700.0, 1000.0, 1500.0] - cross-sections: [0.0, 0.0, 1.95e-22, 4.28e-22, 6.6e-22, 9.11e-22, 1.2e-21, 1.516e-21, - 1.841e-21, 2.13e-21, 2.502e-21, 3.181e-21, 3.869e-21, 4.557e-21, 5.924e-21, - 9.579e-21, 1.1718e-20, 1.6461e-20, 2.0181e-20, 2.2134e-20, 2.3436e-20, 2.2692e-20, - 2.1018e-20, 1.7763e-20, 1.3485e-20, 1.0788e-20, 8.556e-21, 7.44e-21] - threshold: 15.6 + collision: phelps_N2_ionization_N2^+_15.6 electron-collisions: -- target: N2 +- name: phelps_N2_effective_N2_0.0 + target: N2 energy-levels: [0.0, 0.001, 0.002, 0.003, 0.005, 0.007, 0.0085, 0.01, 0.015, 0.02, 0.03, 0.04, 0.05, 0.07, 0.1, 0.12, 0.15, 0.17, 0.2, 0.25, 0.3, 0.35, 0.4, 0.5, 0.7, 1.0, 1.2, 1.3, 1.5, 1.7, 1.9, 2.1, 2.2, 2.5, 2.8, 3.0, 3.3, 3.6, 4.0, 4.5, 5.0, 6.0, @@ -78,7 +139,8 @@ electron-collisions: 9e-20, 8.6e-20, 6.6e-20, 5.8e-20, 4.9e-20, 4.2e-20, 3.3e-20, 2.44e-20, 1.96e-20, 1.55e-20, 1.12e-20, 8.1e-21, 6.3e-21, 4e-21, 2.9e-21, 2.1e-21] kind: effective -- target: N2 +- name: phelps_N2_excitation_N2(rot)_0.02 + target: N2 product: N2(rot) energy-levels: [0.02, 0.03, 0.4, 0.8, 1.2, 1.6, 1.7, 1.8, 1.9, 2.0, 2.1, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.8, 2.9, 3.0, 3.1, 3.2, 3.3, 3.6, 5.0] @@ -87,7 +149,8 @@ electron-collisions: 1.62e-20, 1.38e-20, 1.18e-20, 1.03e-20, 8.4e-21, 6.9e-21, 5e-21, 1.7e-21, 0.0] threshold: 0.02 kind: excitation -- target: N2 +- name: phelps_N2_excitation_N2(v1)_0.29 + target: N2 product: N2(v1) energy-levels: [0.29, 0.3, 0.33, 0.4, 0.75, 0.9, 1.0, 1.1, 1.16, 1.2, 1.22, 1.4, 1.5, 1.6, 1.65, 3.6, 4.0, 5.0, 15.0, 18.0, 20.0, 22.0, 23.0, 25.0, 29.0, 32.0, 50.0, @@ -97,7 +160,8 @@ electron-collisions: 3.5e-22, 4e-22, 6.5e-22, 8.5e-22, 8.5e-22, 6e-22, 3e-22, 1.5e-22, 1.2e-22, 0.0] threshold: 0.29 kind: excitation -- target: N2 +- name: phelps_N2_excitation_N2(v1res)_0.291 + target: N2 product: N2(v1res) energy-levels: [0.0, 0.291, 1.6, 1.65, 1.7, 1.8, 1.9, 2.0, 2.1, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.75, 2.8, 2.9, 3.0, 3.1, 3.2, 3.3, 3.4, 3.5, 3.6, 4.0, 100.0, 1000.0] @@ -107,7 +171,8 @@ electron-collisions: 0.0, 0.0, 0.0] threshold: 0.291 kind: excitation -- target: N2 +- name: phelps_N2_excitation_N2(v2)_0.59 + target: N2 product: N2(v2) energy-levels: [0.0, 0.59, 1.7, 1.8, 1.9, 2.0, 2.1, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.75, 2.8, 2.9, 3.0, 3.1, 3.2, 3.3, 3.4, 3.5, 3.6, 1000.0] @@ -116,7 +181,8 @@ electron-collisions: 6.45e-21, 3.75e-21, 3.45e-21, 3e-21, 2.13e-21, 0.0, 0.0] threshold: 0.59 kind: excitation -- target: N2 +- name: phelps_N2_excitation_N2(v3)_0.88 + target: N2 product: N2(v3) energy-levels: [0.0, 0.88, 1.9, 2.0, 2.1, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.75, 2.8, 2.9, 3.0, 3.1, 3.2, 3.3, 3.4, 1000.0] @@ -125,7 +191,8 @@ electron-collisions: 2.91e-21, 6.15e-22, 0.0, 0.0] threshold: 0.88 kind: excitation -- target: N2 +- name: phelps_N2_excitation_N2(v4)_1.17 + target: N2 product: N2(v4) energy-levels: [0.0, 1.17, 2.0, 2.1, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.75, 2.8, 2.9, 3.0, 3.1, 3.2, 3.3, 1000.0] @@ -133,7 +200,8 @@ electron-collisions: 8.25e-22, 1.2e-20, 1.095e-20, 6.75e-21, 3e-22, 3.3e-21, 3.15e-21, 6e-22, 0.0, 0.0] threshold: 1.17 kind: excitation -- target: N2 +- name: phelps_N2_excitation_N2(v5)_1.47 + target: N2 product: N2(v5) energy-levels: [0.0, 1.47, 2.1, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.75, 2.8, 2.9, 3.0, 3.1, 3.2, 3.3, 3.4, 1000.0] @@ -142,7 +210,8 @@ electron-collisions: 0.0] threshold: 1.47 kind: excitation -- target: N2 +- name: phelps_N2_excitation_N2(v6)_1.76 + target: N2 product: N2(v6) energy-levels: [0.0, 1.76, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.75, 2.8, 2.9, 3.0, 3.1, 3.2, 100.0, 1000.0] @@ -150,7 +219,8 @@ electron-collisions: 4.5e-21, 3.15e-21, 2.46e-21, 4.8e-21, 1.635e-21, 0.0, 0.0, 0.0] threshold: 1.76 kind: excitation -- target: N2 +- name: phelps_N2_excitation_N2(C3)_11.03 + target: N2 product: N2(C3) energy-levels: [11.03, 11.5, 12.0, 12.5, 13.0, 13.5, 13.8, 14.0, 14.2, 14.5, 15.0, 16.0, 17.0, 18.0, 19.0, 20.0, 22.0, 24.0, 26.0, 28.0, 30.0, 36.0, 40.0, 50.0, 70.0, @@ -161,7 +231,8 @@ electron-collisions: 0.0] threshold: 11.03 kind: excitation -- target: N2 +- name: phelps_N2_excitation_N2(E3)_11.87 + target: N2 product: N2(E3) energy-levels: [0.0, 11.87, 11.92, 12.7, 17.0, 19.0, 20.0, 22.0, 24.0, 26.0, 28.0, 30.0, 32.0, 40.0, 50.0, 150.0, 500.0, 1000.0] @@ -169,7 +240,8 @@ electron-collisions: 5.4e-23, 5.4e-23, 4.4e-23, 3.4e-23, 2.7e-23, 1.2e-23, 5e-24, 0.0, 0.0, 0.0] threshold: 11.87 kind: excitation -- target: N2 +- name: phelps_N2_excitation_N2(a''1)_12.25 + target: N2 product: N2(a''1) energy-levels: [0.0, 12.25, 13.0, 15.0, 16.0, 17.0, 18.0, 19.0, 20.0, 22.0, 24.0, 26.0, 30.0, 36.0, 40.0, 50.0, 70.0, 100.0, 150.0, 200.0, 300.0, 500.0, 700.0, @@ -179,7 +251,8 @@ electron-collisions: 6.8e-23, 5e-23, 3e-23, 2.9e-23, 2e-23, 1.3e-23, 1e-23, 8e-24] threshold: 12.25 kind: excitation -- target: N2 +- name: phelps_N2_excitation_N2(SUM)_13.0 + target: N2 product: N2(SUM) energy-levels: [13.0, 14.0, 15.0, 16.0, 17.0, 18.0, 20.0, 22.0, 25.0, 30.0, 40.0, 60.0, 80.0, 100.0, 150.0, 200.0, 250.0, 300.0, 500.0, 700.0, 1000.0] @@ -188,7 +261,8 @@ electron-collisions: 1.05e-20, 9.6e-21, 7.4e-21, 6.4e-21, 5.3e-21] threshold: 13.0 kind: excitation -- target: N2 +- name: phelps_N2_excitation_N2(v7)_2.06 + target: N2 product: N2(v7) energy-levels: [0.0, 2.06, 2.3, 2.4, 2.5, 2.6, 2.7, 2.75, 2.8, 2.9, 3.0, 3.1, 3.2, 3.3, 3.4, 3.5, 100.0, 1000.0] @@ -196,7 +270,8 @@ electron-collisions: 1.8e-21, 6.3e-23, 1.92e-21, 2.04e-21, 7.8e-22, 1.89e-22, 0.0, 0.0, 0.0] threshold: 2.06 kind: excitation -- target: N2 +- name: phelps_N2_excitation_N2(v8)_2.35 + target: N2 product: N2(v8) energy-levels: [0.0, 2.35, 2.5, 2.6, 2.7, 2.75, 2.8, 2.9, 3.0, 3.1, 3.2, 3.3, 3.4, 3.5, 100.0, 1000.0] @@ -204,7 +279,8 @@ electron-collisions: 2.64e-21, 3.75e-22, 6.3e-23, 1.545e-21, 2.52e-22, 0.0, 0.0, 0.0] threshold: 2.35 kind: excitation -- target: N2 +- name: phelps_N2_excitation_N2(A3,v0-4)_6.17 + target: N2 product: N2(A3,v0-4) energy-levels: [6.17, 7.0, 7.8, 8.5, 9.0, 10.0, 11.0, 12.0, 13.0, 14.0, 16.0, 17.0, 18.0, 20.0, 22.0, 24.0, 26.0, 30.0, 34.0, 40.0, 50.0, 70.0, 150.0] @@ -213,7 +289,8 @@ electron-collisions: 5.9e-23, 4.9e-23, 3.9e-23, 3.4e-23, 7e-24, 0.0] threshold: 6.17 kind: excitation -- target: N2 +- name: phelps_N2_excitation_N2(A3,v5-9)_7.0 + target: N2 product: N2(A3,v5-9) energy-levels: [7.0, 7.3, 7.8, 8.5, 9.0, 10.0, 11.0, 12.0, 13.0, 14.0, 16.0, 17.0, 18.0, 20.0, 22.0, 24.0, 26.0, 30.0, 34.0, 40.0, 50.0, 70.0, 150.0] @@ -222,7 +299,8 @@ electron-collisions: 2.5e-22, 2.1e-22, 1.7e-22, 1.4e-22, 2.9e-23, 0.0] threshold: 7.0 kind: excitation -- target: N2 +- name: phelps_N2_excitation_N2(B3)_7.35 + target: N2 product: N2(B3) energy-levels: [0.0, 7.35, 8.0, 9.0, 10.0, 11.0, 12.0, 13.0, 14.0, 15.0, 16.0, 17.0, 18.0, 20.0, 22.0, 26.0, 30.0, 34.0, 40.0, 50.0, 70.0, 150.0, 500.0, 1000.0] @@ -231,7 +309,8 @@ electron-collisions: 9.51e-22, 8.04e-22, 6.77e-22, 5.63e-22, 4.29e-22, 2.68e-22, 6.7e-23, 0.0, 0.0, 0.0] threshold: 7.35 kind: excitation -- target: N2 +- name: phelps_N2_excitation_N2(W3)_7.36 + target: N2 product: N2(W3) energy-levels: [0.0, 7.36, 8.0, 9.0, 10.0, 11.0, 12.0, 14.0, 15.0, 16.0, 17.0, 18.0, 20.0, 22.0, 24.0, 26.0, 28.0, 30.0, 34.0, 40.0, 50.0, 70.0, 100.0, 150.0, 500.0, @@ -242,7 +321,8 @@ electron-collisions: 4.7e-23, 0.0, 0.0, 0.0] threshold: 7.36 kind: excitation -- target: N2 +- name: phelps_N2_excitation_N2(A3,v10-)_7.8 + target: N2 product: N2(A3,v10-) energy-levels: [7.8, 8.1, 8.5, 8.7, 9.0, 10.0, 11.0, 12.0, 13.0, 14.0, 16.0, 17.0, 18.0, 20.0, 22.0, 24.0, 26.0, 30.0, 34.0, 40.0, 50.0, 70.0, 150.0] @@ -251,7 +331,8 @@ electron-collisions: 2.6e-22, 2.1e-22, 1.7e-22, 1.5e-22, 3e-23, 0.0] threshold: 7.8 kind: excitation -- target: N2 +- name: phelps_N2_excitation_N2(B'3)_8.16 + target: N2 product: N2(B'3) energy-levels: [8.16, 9.0, 10.0, 11.0, 12.0, 13.0, 14.0, 15.0, 16.0, 17.0, 18.0, 19.0, 20.0, 22.0, 26.0, 30.0, 34.0, 40.0, 50.0, 70.0, 150.0, 500.0, 1000.0] @@ -260,7 +341,8 @@ electron-collisions: 2.28e-22, 1.94e-22, 1.61e-22, 1.27e-22, 6.7e-23, 0.0, 0.0, 0.0] threshold: 8.16 kind: excitation -- target: N2 +- name: phelps_N2_excitation_N2(a'1)_8.4 + target: N2 product: N2(a'1) energy-levels: [8.4, 9.0, 11.0, 13.0, 14.0, 15.0, 16.0, 17.0, 18.0, 19.0, 20.0, 24.0, 30.0, 40.0, 50.0, 70.0, 150.0, 500.0, 1000.0] @@ -269,7 +351,8 @@ electron-collisions: 1.01e-22, 6.7e-23, 0.0, 0.0] threshold: 8.4 kind: excitation -- target: N2 +- name: phelps_N2_excitation_N2(a1)_8.55 + target: N2 product: N2(a1) energy-levels: [0.0, 8.55, 9.0, 14.0, 15.0, 16.0, 17.0, 18.0, 19.0, 20.0, 24.0, 26.0, 30.0, 40.0, 50.0, 70.0, 100.0, 150.0, 200.0, 250.0, 300.0, 500.0, 700.0, 1000.0] @@ -279,7 +362,8 @@ electron-collisions: 6e-23, 4.2e-23] threshold: 8.55 kind: excitation -- target: N2 +- name: phelps_N2_excitation_N2(w1)_8.89 + target: N2 product: N2(w1) energy-levels: [0.0, 8.89, 9.0, 10.0, 11.0, 12.0, 13.0, 14.0, 15.0, 16.0, 17.0, 18.0, 20.0, 22.0, 30.0, 38.0, 50.0, 150.0, 500.0, 1000.0] @@ -288,7 +372,8 @@ electron-collisions: 4.7e-23, 0.0, 0.0, 0.0] threshold: 8.89 kind: excitation -- target: N2 +- name: phelps_N2_ionization_N2^+(B2SIGMA)_18.8 + target: N2 product: N2^+(B2SIGMA) energy-levels: [18.8, 19.0, 19.6, 20.0, 30.0, 35.0, 40.0, 45.0, 50.0, 60.0, 80.0, 90.0, 100.0, 150.0, 300.0, 500.0, 700.0, 1000.0, 1500.0, 2000.0, 4000.0, 7000.0, @@ -298,7 +383,20 @@ electron-collisions: 1.03e-21, 8.3e-22, 6.4e-22, 4.7e-22, 3.7e-22, 2.15e-22, 1.38e-22, 1.04e-22] threshold: 18.8 kind: ionization -- target: O2 +- name: phelps_N2_ionization_N2^+_15.6 + target: N2 + product: N2^+ + energy-levels: [0.0, 15.6, 16.0, 16.5, 17.0, 17.5, 18.0, 18.5, 19.0, 19.5, 20.0, 21.0, + 22.0, 23.0, 25.0, 30.0, 34.0, 45.0, 60.0, 75.0, 100.0, 150.0, 200.0, 300.0, 500.0, + 700.0, 1000.0, 1500.0] + cross-sections: [0.0, 0.0, 1.95e-22, 4.28e-22, 6.6e-22, 9.11e-22, 1.2e-21, 1.516e-21, + 1.841e-21, 2.13e-21, 2.502e-21, 3.181e-21, 3.869e-21, 4.557e-21, 5.924e-21, + 9.579e-21, 1.1718e-20, 1.6461e-20, 2.0181e-20, 2.2134e-20, 2.3436e-20, 2.2692e-20, + 2.1018e-20, 1.7763e-20, 1.3485e-20, 1.0788e-20, 8.556e-21, 7.44e-21] + threshold: 15.6 + kind: ionization +- name: phelps_O2_attachment_O^-+O_0.0 + target: O2 energy-levels: [4.4, 4.9, 5.38, 5.86, 6.1, 6.48, 6.77, 7.05, 7.3, 7.53, 7.77, 8.0, 8.25, 8.73, 9.2, 9.68, 10.15, 11.35, 10000.0] cross-sections: [0.0, 0.0, 2.3e-23, 7.2e-23, 1.08e-22, 1.38e-22, 1.52e-22, 1.56e-22, @@ -307,7 +405,8 @@ electron-collisions: threshold: 0.0 product: O^-+O kind: attachment -- target: O2 +- name: phelps_O2_effective_O2_0.0 + target: O2 energy-levels: [0.0, 0.001, 0.002, 0.003, 0.005, 0.007, 0.0085, 0.01, 0.015, 0.02, 0.03, 0.04, 0.05, 0.07, 0.1, 0.12, 0.15, 0.17, 0.2, 0.25, 0.3, 0.35, 0.4, 0.5, 0.7, 1.0, 1.2, 1.3, 1.5, 1.7, 1.9, 2.1, 2.2, 2.5, 2.8, 3.0, 3.3, 3.6, 4.0, 4.5, 5.0, 6.0, @@ -322,7 +421,8 @@ electron-collisions: 6.5e-20, 6.7e-20, 6e-20, 4.9e-20, 3.6e-20, 2.9e-20, 2.12e-20, 1.48e-20, 1.14e-20, 7.9e-21, 5.1e-21, 3.8e-21, 2.8e-21] kind: effective -- target: O2 +- name: phelps_O2_excitation_O2(rot)_0.02 + target: O2 product: O2(rot) energy-levels: [0.07, 0.08, 0.1, 0.2, 0.21, 0.22, 0.32, 0.33, 0.35, 0.44, 0.45, 0.47, 0.56, 0.57, 0.59, 0.68, 0.69, 0.71, 0.79, 0.8, 0.81, 0.9, 0.91, 0.93, 1.02, 1.03, @@ -334,7 +434,8 @@ electron-collisions: 0.0, 0.0, 2.4e-22, 0.0, 0.0, 1.2e-22, 0.0, 0.0, 4.8e-23, 0.0] threshold: 0.02 kind: excitation -- target: O2 +- name: phelps_O2_excitation_O2(v1)_0.19 + target: O2 product: O2(v1) energy-levels: [0.0, 0.19, 0.2, 0.21, 0.23, 0.32, 0.33, 0.35, 0.44, 0.45, 0.47, 0.56, 0.57, 0.59, 0.68, 0.69, 0.71, 0.79, 0.8, 0.82, 0.9, 0.91, 0.93, 1.02, 1.03, 1.05, @@ -346,7 +447,8 @@ electron-collisions: 5.5e-23, 0.0, 0.0, 1.9e-23, 0.0, 0.0, 6e-24, 0.0, 0.0] threshold: 0.19 kind: excitation -- target: O2 +- name: phelps_O2_excitation_O2(v1res)_0.19 + target: O2 product: O2(v1res) energy-levels: [4.0, 5.0, 6.0, 7.0, 8.0, 9.0, 10.0, 11.0, 12.0, 13.0, 14.0, 15.0, 20.0, 45.0] @@ -354,7 +456,8 @@ electron-collisions: 1.86e-21, 1.43e-21, 1.02e-21, 7.1e-22, 4e-22, 1e-22, 0.0] threshold: 0.19 kind: excitation -- target: O2 +- name: phelps_O2_excitation_O2(v2)_0.38 + target: O2 product: O2(v2) energy-levels: [0.0, 0.38, 0.44, 0.45, 0.47, 0.56, 0.57, 0.59, 0.68, 0.69, 0.71, 0.79, 0.8, 0.82, 0.9, 0.91, 0.93, 1.02, 1.03, 1.05, 1.13, 1.14, 1.16, 1.23, 1.24, 1.26, @@ -366,7 +469,8 @@ electron-collisions: 0.0, 0.0, 0.0, 0.0, 0.0] threshold: 0.38 kind: excitation -- target: O2 +- name: phelps_O2_excitation_O2(v2res)_0.38 + target: O2 product: O2(v2res) energy-levels: [4.0, 5.0, 6.0, 7.0, 8.0, 9.0, 10.0, 11.0, 12.0, 13.0, 14.0, 15.0, 20.0, 45.0] @@ -374,7 +478,8 @@ electron-collisions: 7.3e-22, 5.1e-22, 2.8e-22, 1.3e-22, 5e-23, 0.0] threshold: 0.38 kind: excitation -- target: O2 +- name: phelps_O2_excitation_O2(v3)_0.57 + target: O2 product: O2(v3) energy-levels: [0.0, 0.57, 0.68, 0.69, 0.71, 0.79, 0.8, 0.82, 0.9, 0.91, 0.93, 1.02, 1.03, 1.05, 1.13, 1.14, 1.16, 1.23, 1.24, 1.26, 1.34, 1.35, 1.37, 1.44, 1.45, 1.47, @@ -387,7 +492,8 @@ electron-collisions: 0.0] threshold: 0.57 kind: excitation -- target: O2 +- name: phelps_O2_excitation_O2(v4)_0.75 + target: O2 product: O2(v4) energy-levels: [0.0, 0.75, 0.79, 0.8, 0.82, 0.9, 0.91, 0.93, 1.02, 1.03, 1.05, 1.13, 1.14, 1.16, 1.23, 1.24, 1.26, 1.34, 1.35, 1.37, 1.44, 1.45, 1.47, 1.54, 1.55, 1.57, @@ -398,7 +504,8 @@ electron-collisions: 3.13e-22, 2.5e-22, 1.75e-22, 8.8e-23, 0.0, 0.0] threshold: 0.75 kind: excitation -- target: O2 +- name: phelps_O2_excitation_O2(a1)_0.977 + target: O2 product: O2(a1) energy-levels: [0.977, 1.5, 2.0, 3.0, 3.5, 4.0, 5.0, 5.62, 5.91, 6.19, 6.53, 6.99, 7.61, 7.89, 8.96, 10.04, 13.0, 15.1, 17.5, 20.5, 24.9, 30.9, 41.0, 45.0, 10000.0] @@ -407,7 +514,8 @@ electron-collisions: 5.27e-22, 4.55e-22, 3.87e-22, 3.24e-22, 2.56e-22, 1.96e-22, 1.37e-22, 1.2e-22, 0.0] threshold: 0.977 kind: excitation -- target: O2 +- name: phelps_O2_excitation_O2(b1)_1.627 + target: O2 product: O2(b1) energy-levels: [1.627, 2.0, 3.0, 3.5, 4.0, 5.0, 5.69, 6.54, 7.34, 8.41, 9.26, 10.0, 13.0, 14.9, 17.0, 19.4, 20.7, 22.5, 24.0, 28.0, 35.1, 41.9, 45.1, 1000.0] @@ -416,21 +524,24 @@ electron-collisions: 1.25e-22, 1.25e-22, 1.1e-22, 1e-22, 8e-23, 6.3e-23, 1.8e-23, 5e-24, 0.0] threshold: 1.627 kind: excitation -- target: O2 +- name: phelps_O2_excitation_O2(4.5eV)_4.5 + target: O2 product: O2(4.5eV) energy-levels: [4.5, 4.8, 5.0, 5.5, 6.0, 6.5, 7.0, 7.5, 8.0, 9.0, 10.0, 12.0, 15.0] cross-sections: [0.0, 3e-23, 9e-23, 3e-22, 6.5e-22, 8.5e-22, 9.5e-22, 1e-21, 1e-21, 8.5e-22, 7e-22, 4.5e-22, 0.0] threshold: 4.5 kind: excitation -- target: O2 +- name: phelps_O2_excitation_O2(6.0eV)_6.0 + target: O2 product: O2(6.0eV) energy-levels: [6.0, 7.0, 7.8, 9.0, 10.0, 12.0, 15.0, 17.0, 20.0, 45.0, 100.0] cross-sections: [0.0, 1.5e-21, 2.3e-21, 2.3e-21, 2.1e-21, 1.65e-21, 1.05e-21, 6.5e-22, 4.75e-22, 1.9e-22, 0.0] threshold: 6.0 kind: excitation -- target: O2 +- name: phelps_O2_excitation_O2(8.4eV)_8.4 + target: O2 product: O2(8.4eV) energy-levels: [8.4, 9.4, 30.0, 50.0, 100.0, 150.0, 200.0, 300.0, 500.0, 700.0, 1000.0, 1500.0, 2000.0, 3000.0, 5000.0, 7000.0, 10000.0] @@ -438,7 +549,8 @@ electron-collisions: 1.09e-21, 8e-22, 5.8e-22, 4.2e-22, 3.3e-22, 2.4e-22, 1.6e-22, 1.2e-22, 9e-23] threshold: 8.4 kind: excitation -- target: O2 +- name: phelps_O2_excitation_O2(9.97eV)_9.97 + target: O2 product: O2(9.97eV) energy-levels: [10.0, 20.0, 30.0, 40.0, 50.0, 60.0, 70.0, 80.0, 100.0, 120.0, 150.0, 170.0, 200.0, 300.0, 500.0, 700.0, 1000.0, 1500.0] @@ -446,3 +558,26 @@ electron-collisions: 5e-22, 4e-22, 3.5e-22, 3e-22, 2e-22, 1.2e-22, 8e-23, 5e-23, 0.0] threshold: 9.97 kind: excitation +- name: phelps_O2_excitation_O2^+_12.06 + target: O2 + product: O2^+ + energy-levels: [12.06, 13.0, 18.0, 28.0, 38.0, 48.0, 58.0, 68.0, 78.0, 88.0, 100.0, + 150.0, 200.0, 300.0, 500.0, 700.0, 1000.0, 1500.0, 2000.0, 3000.0, 5000.0, 7000.0, + 10000.0] + cross-sections: [0.0, 2.3e-22, 2e-21, 7.4e-21, 1.32e-20, 1.8e-20, 2.1e-20, 2.33e-20, + 2.5e-20, 2.6e-20, 2.7e-20, 2.7e-20, 2.5e-20, 2.17e-20, 1.66e-20, 1.35e-20, 1.04e-20, + 7.6e-21, 6e-21, 4.2e-21, 2.7e-21, 2e-21, 1.4e-21] + threshold: 12.06 + kind: ionization +- name: phelps_O2_attachement_O2^-_0.0 + target: O2 + product: O2^- + energy-levels: [0.0, 0.058, 0.073, 0.083, 0.089, 0.095, 0.103, 0.109, 0.15, 0.17, 0.2, + 0.21, 0.23, 0.32, 0.33, 0.35, 0.44, 0.45, 0.47, 0.56, 0.57, 0.59, 0.68, 0.69, 0.71, + 0.79, 0.8, 0.82, 0.9, 0.91, 0.93, 1.02, 1.03, 1.05, 1.5, 10000.0] + cross-sections: [0.0, 0.0, 5.60795e-41, 1.80256e-40, 4.20596e-41, 8.41193e-41, + 1.80256e-40, 0.0, 0.0, 0.0, 0.0, 3.56506e-41, 0.0, 0.0, 2.30327e-41, 0.0, 0.0, + 1.45206e-41, 0.0, 0.0, 1.10156e-41, 0.0, 0.0, 8.01136e-42, 0.0, 0.0, 7.00994e-42, + 0.0, 0.0, 5.50781e-42, 0.0, 0.0, 4.20596e-42, 0.0, 0.0, 0.0] + threshold: 0.0 + kind: attachment \ No newline at end of file diff --git a/methane-plasma-pavan-2023.yaml b/methane-plasma-pavan-2023.yaml index dc0ca5e..d153085 100644 --- a/methane-plasma-pavan-2023.yaml +++ b/methane-plasma-pavan-2023.yaml @@ -17,7 +17,7 @@ description: |- Virginia: American Institute of Aeronautics and Astronautics, Jan. 2023, pp. 1-15. DOI: 10.2514/6.2023-2056. -cantera-version: 3.2.0 +cantera-version: 3.4.0 date: Thu, 17 Jul 2025 23:47:45 -0400 units: {length: cm, time: s, quantity: mol, activation-energy: cal/mol} @@ -35,7 +35,6 @@ phases: reactions: - gri30.yaml/reactions: all - reactions: all - - collisions: all state: {T: 300.0, P: 1 atm} electron-energy-distribution: type: Boltzmann-two-term @@ -44,6 +43,17 @@ phases: 18.0, 19.0, 20.0, 21.0, 22.0, 23.0, 24.0, 25.0, 26.0, 27.0, 28.0, 29.0, 30.0, 31.0, 32.0, 33.0, 34.0, 35.0, 36.0, 37.0, 38.0, 39.0, 40.0] + # electron-energy-distribution: + # type: Boltzmann-two-term + # initial_max_energy_level: 60.0 + # initial_number_of_energy_grid_cells: 201 + # energy_levels_distribution: Linear + # energy_grid_adaptation: + # enabled: true + # min_decay_decades: 13.0 + # max_decay_decades: 15.0 + # update_factor: 0.1 + # max_iterations: 1000 species: - name: e @@ -764,345 +774,406 @@ reactions: [0.08098833815161564], [-0.05043366407982257]] -collisions: -- equation: N2 + e => e + N2 +# collisional reactions +- equation: e + N2 => e + N2(v1) type: electron-collision-plasma - energy-levels: [0.0, 0.01, 0.015, 0.02, 0.03, 0.04, 0.05, 0.07, 0.1, 0.12, 0.15, - 0.17, 0.2, 0.25, 0.3, 0.35, 0.4, 0.5, 0.7, 1.0, 1.2, 1.3, 1.5, 1.7, 1.9, 2.1, - 2.2, 2.5, 2.8, 3.0, 3.3, 3.6, 4.0, 4.5, 5.0, 6.0, 7.0, 8.0, 10.0, 12.0, 15.0, - 17.0, 20.0, 25.0, 30.0, 50.0, 75.0, 100.0, 150.0, 200.0, 300.0, 500.0, 700.0, - 1000.0] - cross-sections: [1.1e-20, 2.19e-20, 2.55e-20, 2.85e-20, 3.38e-20, 3.82e-20, 4.3e-20, - 5.08e-20, 5.92e-20, 6.42e-20, 7.08e-20, 7.38e-20, 7.88e-20, 8.48e-20, 8.98e-20, - 9.36e-20, 9.67e-20, 9.87e-20, 9.97e-20, 9.96e-20, 1.034e-19, 1.092e-19, 1.187e-19, - 1.347e-19, 1.641e-19, 1.685e-19, 1.802e-19, 1.792e-19, 2.1e-19, 1.72e-19, 1.53e-19, - 1.396e-19, 1.242e-19, 1.119e-19, 1.086e-19, 1.036e-19, 1e-19, 1.02e-19, 9.9e-20, - 9.5e-20, 8.7e-20, 8.26e-20, 7.6e-20, 6.7e-20, 5.9e-20, 3.8e-20, 2.56e-20, 1.8e-20, - 1.13e-20, 8e-21, 4.8e-21, 2.3e-21, 1.43e-21, 7e-22] -- equation: N2 + e => e + N2(v1) - type: electron-collision-plasma - energy-levels: [1.6, 1.65, 1.7, 1.8, 1.9, 2.0, 2.1, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, - 2.75, 2.8, 2.9, 3.0, 3.1, 3.2, 3.3, 3.4, 3.5, 3.6, 4.0] - cross-sections: [0.0, 2.7e-21, 3.15e-21, 5.4e-21, 1.485e-20, 4.8e-20, 2.565e-20, - 1.2e-20, 4.5e-20, 2.76e-20, 1.59e-20, 3.15e-20, 1.545e-20, 6e-21, 1.35e-20, 5.25e-21, - 8.7e-21, 1.17e-20, 8.55e-21, 6.6e-21, 6e-21, 5.85e-21, 5.7e-21, 0.0] -- equation: N2 + e => e + N2(v2) + collision: siglo_N2_excitation_N2(v1)_1.6 + +- equation: e + N2 => e + N2(v2) type: electron-collision-plasma - energy-levels: [1.7, 1.8, 1.9, 2.0, 2.1, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.75, 2.8, - 2.9, 3.0, 3.1, 3.2, 3.3, 3.4, 3.5, 3.6] - cross-sections: [0.0, 1.5e-22, 6.3e-21, 1.935e-20, 3.3e-20, 1.47e-20, 5.4e-21, 2.115e-20, - 3e-20, 5.4e-21, 1.05e-20, 1.725e-20, 1.275e-20, 3.3e-21, 9e-21, 6.45e-21, 3.75e-21, - 3.45e-21, 3e-21, 2.13e-21, 0.0] -- equation: N2 + e => e + N2(v3) + collision: siglo_N2_excitation_N2(v2)_1.7 + +- equation: e + N2 => e + N2(v3) type: electron-collision-plasma - energy-levels: [1.9, 2.0, 2.1, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.75, 2.8, 2.9, 3.0, - 3.1, 3.2, 3.3, 3.4] - cross-sections: [0.0, 9.6e-21, 2.055e-20, 2.7e-20, 1.695e-20, 7.5e-22, 9.6e-21, - 1.47e-20, 4.5e-21, 9.6e-21, 5.4e-21, 8.55e-21, 4.05e-21, 2.82e-21, 2.91e-21, 6.15e-22, - 0.0] -- equation: N2 + e => e + N2(v4) + collision: siglo_N2_excitation_N2(v3)_1.9 + +- equation: e + N2 => e + N2(v4) type: electron-collision-plasma - energy-levels: [2.0, 2.1, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.75, 2.8, 2.9, 3.0, 3.1, - 3.2, 3.3] - cross-sections: [0.0, 2.025e-21, 1.515e-20, 2.385e-20, 1.44e-20, 5.55e-21, 8.25e-22, - 1.2e-20, 1.095e-20, 6.75e-21, 3e-22, 3.3e-21, 3.15e-21, 6e-22, 0.0] -- equation: N2 + e => e + N2(v5) + collision: siglo_N2_excitation_N2(v4)_2.0 + +- equation: e + N2 => e + N2(v5) type: electron-collision-plasma - energy-levels: [2.1, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.75, 2.8, 2.9, 3.0, 3.1, 3.2, - 3.3, 3.4] - cross-sections: [0.0, 8.25e-21, 1.23e-20, 1.53e-20, 1.44e-20, 3.45e-21, 2.25e-22, - 3.45e-21, 5.4e-21, 6.6e-21, 2.175e-21, 1.05e-21, 3.15e-21, 1.035e-21, 0.0] -- equation: N2 + e => e + N2(v6) + collision: siglo_N2_excitation_N2(v5)_2.1 + +- equation: e + N2 => e + N2(v6) type: electron-collision-plasma - energy-levels: [2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.75, 2.8, 2.9, 3.0, 3.1, 3.2] - cross-sections: [0.0, 6.3e-23, 1.125e-20, 1.74e-20, 1.38e-20, 7.8e-21, 4.5e-21, - 3.15e-21, 2.46e-21, 4.8e-21, 1.635e-21, 0.0] -- equation: N2 + e => e + N2(v7) + collision: siglo_N2_excitation_N2(v6)_2.2 + +- equation: e + N2 => e + N2(v7) type: electron-collision-plasma - energy-levels: [2.3, 2.4, 2.5, 2.6, 2.7, 2.75, 2.8, 2.9, 3.0, 3.1, 3.2, 3.3, 3.4, - 3.5] - cross-sections: [0.0, 1.26e-22, 3.9e-21, 6.6e-21, 9.6e-21, 7.95e-21, 6e-21, 1.8e-21, - 6.3e-23, 1.92e-21, 2.04e-21, 7.8e-22, 1.89e-22, 0.0] -- equation: N2 + e => e + N2(v8) + collision: siglo_N2_excitation_N2(v7)_2.3 + +- equation: e + N2 => e + N2(v8) type: electron-collision-plasma - energy-levels: [2.5, 2.6, 2.7, 2.75, 2.8, 2.9, 3.0, 3.1, 3.2, 3.3, 3.4, 3.5] - cross-sections: [0.0, 1.89e-22, 3.6e-21, 3.6e-21, 3.3e-21, 3.45e-21, 2.64e-21, 3.75e-22, - 6.3e-23, 1.545e-21, 2.52e-22, 0.0] -- equation: N2 + e => e + N2(A) + collision: siglo_N2_excitation_N2(v8)_2.5 + +- equation: e + N2 => e + N2(A) type: electron-collision-plasma - energy-levels: [6.17, 7.0, 7.8, 8.5, 9.0, 10.0, 11.0, 12.0, 13.0, 14.0, 16.0, 17.0, - 18.0, 20.0, 22.0, 24.0, 26.0, 30.0, 34.0, 40.0, 50.0, 70.0, 150.0] - cross-sections: [0.0, 1e-23, 2.8e-23, 4.3e-23, 5.2e-23, 8.2e-23, 1e-22, 1.2e-22, - 1.3e-22, 1.4e-22, 1.5e-22, 1.5e-22, 1.4e-22, 1.2e-22, 1e-22, 8.9e-23, 7.6e-23, - 5.9e-23, 4.9e-23, 3.9e-23, 3.4e-23, 7e-24, 0.0] + collision: siglo_N2_excitation_N2(A)_6.17 duplicate: true -- equation: N2 + e => e + N2(A) + +- equation: e + N2 => e + N2(A) type: electron-collision-plasma - energy-levels: [7.0, 7.3, 7.8, 8.5, 9.0, 10.0, 11.0, 12.0, 13.0, 14.0, 16.0, 17.0, - 18.0, 20.0, 22.0, 24.0, 26.0, 30.0, 34.0, 40.0, 50.0, 70.0, 150.0] - cross-sections: [0.0, 2e-23, 5e-23, 1.5e-22, 2.2e-22, 3.4e-22, 4.3e-22, 5e-22, 5.5e-22, - 6e-22, 6.5e-22, 6.5e-22, 6.2e-22, 5.3e-22, 4.5e-22, 3.8e-22, 3.3e-22, 2.5e-22, - 2.1e-22, 1.7e-22, 1.4e-22, 2.9e-23, 0.0] + collision: siglo_N2_excitation_N2(A)_7.0 duplicate: true -- equation: N2 + e => e + N2(B) + +- equation: e + N2 => e + N2(B) type: electron-collision-plasma - energy-levels: [7.35, 8.0, 9.0, 10.0, 11.0, 12.0, 13.0, 14.0, 15.0, 16.0, 17.0, - 18.0, 20.0, 22.0, 26.0, 30.0, 34.0, 40.0, 50.0, 70.0, 150.0] - cross-sections: [0.0, 3.62e-22, 9.38e-22, 1.508e-21, 1.863e-21, 2.003e-21, 1.99e-21, - 1.816e-21, 1.615e-21, 1.447e-21, 1.307e-21, 1.199e-21, 1.112e-21, 9.51e-22, 8.04e-22, - 6.77e-22, 5.63e-22, 4.29e-22, 2.68e-22, 6.7e-23, 0.0] + collision: siglo_N2_excitation_N2(B)_7.35 duplicate: true -- equation: N2 + e => e + N2(B) + +- equation: e + N2 => e + N2(B) type: electron-collision-plasma - energy-levels: [7.36, 8.0, 9.0, 10.0, 11.0, 12.0, 14.0, 15.0, 16.0, 17.0, 18.0, - 20.0, 22.0, 24.0, 26.0, 28.0, 30.0, 34.0, 40.0, 50.0, 70.0, 100.0, 150.0] - cross-sections: [0.0, 1.8e-23, 4.96e-22, 8.04e-22, 1.112e-21, 1.427e-21, 2.05e-21, - 2.352e-21, 2.546e-21, 2.519e-21, 2.345e-21, 1.776e-21, 1.32e-21, 1.025e-21, 8.44e-22, - 7.24e-22, 6.3e-22, 4.96e-22, 3.48e-22, 2.01e-22, 1.01e-22, 4.7e-23, 0.0] + collision: siglo_N2_excitation_N2(B)_7.36 duplicate: true -- equation: N2 + e => e + N2(A) + +- equation: e + N2 => e + N2(A) type: electron-collision-plasma - energy-levels: [7.8, 8.1, 8.5, 8.7, 9.0, 10.0, 11.0, 12.0, 13.0, 14.0, 16.0, 17.0, - 18.0, 20.0, 22.0, 24.0, 26.0, 30.0, 34.0, 40.0, 50.0, 70.0, 150.0] - cross-sections: [0.0, 1.5e-23, 4e-23, 7e-23, 1.1e-22, 2.9e-22, 4.4e-22, 5.1e-22, - 5.6e-22, 6e-22, 6.6e-22, 6.7e-22, 6.3e-22, 5.4e-22, 4.6e-22, 3.9e-22, 3.3e-22, - 2.6e-22, 2.1e-22, 1.7e-22, 1.5e-22, 3e-23, 0.0] + collision: siglo_N2_excitation_N2(A)_7.8 duplicate: true -- equation: N2 + e => e + N2(B) + +- equation: e + N2 => e + N2(B) type: electron-collision-plasma - energy-levels: [8.16, 9.0, 10.0, 11.0, 12.0, 13.0, 14.0, 15.0, 16.0, 17.0, 18.0, - 19.0, 20.0, 22.0, 26.0, 30.0, 34.0, 40.0, 50.0, 70.0, 150.0] - cross-sections: [0.0, 1.07e-22, 2.35e-22, 3.69e-22, 4.96e-22, 6.3e-22, 7.57e-22, - 8.38e-22, 7.64e-22, 6.16e-22, 4.89e-22, 4.09e-22, 3.62e-22, 3.15e-22, 2.68e-22, - 2.28e-22, 1.94e-22, 1.61e-22, 1.27e-22, 6.7e-23, 0.0] + collision: siglo_N2_excitation_N2(B)_8.16 duplicate: true -- equation: N2 + e => e + N2(a') + +- equation: e + N2 => e + N2(a') type: electron-collision-plasma - energy-levels: [8.4, 9.0, 11.0, 13.0, 14.0, 15.0, 16.0, 17.0, 18.0, 19.0, 20.0, - 24.0, 30.0, 40.0, 50.0, 70.0, 150.0, 500.0] - cross-sections: [0.0, 6.7e-23, 3.02e-22, 5.36e-22, 6.43e-22, 6.97e-22, 5.7e-22, - 4.29e-22, 3.48e-22, 3.08e-22, 2.75e-22, 2.01e-22, 1.54e-22, 1.24e-22, 1.21e-22, - 1.01e-22, 6.7e-23, 0.0] + collision: siglo_N2_excitation_N2(a')_8.4 duplicate: true -- equation: N2 + e => e + N2(a') + +- equation: e + N2 => e + N2(a') type: electron-collision-plasma - energy-levels: [8.55, 9.0, 14.0, 15.0, 16.0, 17.0, 18.0, 19.0, 20.0, 24.0, 26.0, - 30.0, 40.0, 50.0, 70.0, 100.0, 150.0, 200.0, 250.0, 300.0, 500.0, 700.0, 1000.0] - cross-sections: [0.0, 1.27e-22, 1.474e-21, 1.715e-21, 1.916e-21, 2.023e-21, 1.99e-21, - 1.923e-21, 1.849e-21, 1.621e-21, 1.528e-21, 1.367e-21, 1.065e-21, 8.51e-22, 6.03e-22, - 4.02e-22, 2.68e-22, 2.01e-22, 1.61e-22, 1.34e-22, 8.2e-23, 6e-23, 4.2e-23] + collision: siglo_N2_excitation_N2(a')_8.55 duplicate: true -- equation: N2 + e => e + N2(a') + +- equation: e + N2 => e + N2(a') type: electron-collision-plasma - energy-levels: [8.89, 9.0, 10.0, 11.0, 12.0, 13.0, 14.0, 15.0, 16.0, 17.0, 18.0, - 20.0, 22.0, 30.0, 38.0, 50.0, 150.0] - cross-sections: [0.0, 1.3e-23, 2.61e-22, 4.76e-22, 6.63e-22, 7.84e-22, 7.71e-22, - 6.7e-22, 5.43e-22, 4.42e-22, 3.75e-22, 2.88e-22, 2.41e-22, 1.54e-22, 9.4e-23, - 4.7e-23, 0.0] + collision: siglo_N2_excitation_N2(a')_8.89 duplicate: true -- equation: N2 + e => e + N2(C) + +- equation: e + N2 => e + N2(C) type: electron-collision-plasma - energy-levels: [11.03, 11.5, 12.0, 12.5, 13.0, 13.5, 13.8, 14.0, 14.2, 14.5, 15.0, - 16.0, 17.0, 18.0, 19.0, 20.0, 22.0, 24.0, 26.0, 28.0, 30.0, 36.0, 40.0, 50.0, - 70.0, 100.0, 150.0] - cross-sections: [0.0, 4.05e-22, 9.3e-22, 1.965e-21, 4.35e-21, 7.36e-21, 9.3e-21, - 9.75e-21, 9.6e-21, 9.45e-21, 8.25e-21, 6.45e-21, 5.25e-21, 4.5e-21, 4.05e-21, - 3.75e-21, 3.15e-21, 2.655e-21, 2.25e-21, 2.085e-21, 1.665e-21, 1.17e-21, 9.45e-22, - 5.85e-22, 2.25e-22, 2.3e-23, 0.0] + collision: siglo_N2_excitation_N2(C)_11.03 duplicate: true -- equation: N2 + e => e + N2(C) + +- equation: e + N2 => e + N2(C) type: electron-collision-plasma - energy-levels: [11.87, 11.92, 12.7, 17.0, 19.0, 20.0, 22.0, 24.0, 26.0, 28.0, 30.0, - 32.0, 40.0, 50.0, 150.0] - cross-sections: [0.0, 4.96e-22, 7e-24, 3.4e-23, 4.2e-23, 4.7e-23, 5.2e-23, 5.4e-23, - 5.4e-23, 4.4e-23, 3.4e-23, 2.7e-23, 1.2e-23, 5e-24, 0.0] + collision: siglo_N2_excitation_N2(C)_11.87 duplicate: true -- equation: N2 + e => e + e + N2+ - type: electron-collision-plasma - energy-levels: [15.6, 16.0, 16.5, 17.0, 17.5, 18.0, 18.5, 19.0, 19.5, 20.0, 21.0, - 22.0, 23.0, 25.0, 30.0, 34.0, 45.0, 60.0, 75.0, 100.0, 150.0, 200.0, 300.0, 500.0, - 700.0, 1000.0] - cross-sections: [0.0, 2.1e-22, 4.6e-22, 7.1e-22, 9.8e-22, 1.29e-21, 1.63e-21, 1.98e-21, - 2.29e-21, 2.69e-21, 3.42e-21, 4.16e-21, 4.9e-21, 6.37e-21, 1.03e-20, 1.26e-20, - 1.77e-20, 2.17e-20, 2.38e-20, 2.52e-20, 2.44e-20, 2.26e-20, 1.91e-20, 1.45e-20, - 1.16e-20, 9.2e-21] - -- equation: O2 + e => e + O2 + +- equation: e + N2 => e + e + N2+ type: electron-collision-plasma - energy-levels: [0.0, 0.001, 0.002, 0.003, 0.005, 0.007, 0.0085, 0.01, 0.015, 0.02, - 0.03, 0.04, 0.05, 0.07, 0.1, 0.12, 0.15, 0.17, 0.2, 0.25, 0.3, 0.35, 0.4, 0.5, - 0.7, 1.0, 1.2, 1.3, 1.5, 1.7, 1.9, 2.1, 2.2, 2.5, 2.8, 3.0, 3.3, 3.6, 4.0, 4.5, - 5.0, 6.0, 7.0, 8.0, 10.0, 12.0, 15.0, 17.0, 20.0, 25.0, 30.0, 50.0, 75.0, 100.0, - 150.0, 200.0, 300.0, 500.0, 700.0, 1000.0, 1500.0, 2000.0, 3000.0, 5000.0, 7000.0, - 10000.0] - cross-sections: [3.5e-21, 3.5e-21, 3.6e-21, 4e-21, 5e-21, 5.8e-21, 6.4e-21, 7e-21, - 8.7e-21, 9.9e-21, 1.24e-20, 1.44e-20, 1.6e-20, 2.1e-20, 2.5e-20, 2.8e-20, 3.1e-20, - 3.3e-20, 3.6e-20, 4.1e-20, 4.5e-20, 4.7e-20, 5.2e-20, 5.7e-20, 6.1e-20, 7.2e-20, - 7.9e-20, 7.9e-20, 7.6e-20, 7.3e-20, 6.9e-20, 6.6e-20, 6.5e-20, 6.1e-20, 5.8e-20, - 5.7e-20, 5.5e-20, 5.45e-20, 5.5e-20, 5.55e-20, 5.6e-20, 6e-20, 6.6e-20, 7.1e-20, - 8e-20, 8.5e-20, 8.8e-20, 8.7e-20, 8.6e-20, 8.2e-20, 8e-20, 7.7e-20, 6.8e-20, 6.5e-20, - 6.7e-20, 6e-20, 4.9e-20, 3.6e-20, 2.9e-20, 2.12e-20, 1.48e-20, 1.14e-20, 7.9e-21, - 5.1e-21, 3.8e-21, 2.8e-21] -- equation: O2 + e => e + O + O + collision: siglo_N2_ionization_N2^+_15.6 + +- equation: e + O2 => e + O + O type: electron-collision-plasma - energy-levels: [6.0, 7.0, 7.8, 9.0, 10.0, 12.0, 15.0, 17.0, 20.0, 45.0, 100.0] - cross-sections: [0.0, 1.5e-21, 2.3e-21, 2.3e-21, 2.1e-21, 1.65e-21, 1.05e-21, 6.5e-22, - 4.75e-22, 1.9e-22, 0.0] + collision: phelps_O2_dissociation_O+O_6.0 duplicate: true -- equation: O2 + e => e + O + O + +- equation: e + O2 => e + O + O type: electron-collision-plasma - energy-levels: [8.4, 9.4, 30.0, 50.0, 100.0, 150.0, 200.0, 300.0, 500.0, 700.0, - 1000.0, 1500.0, 2000.0, 3000.0, 5000.0, 7000.0, 10000.0] - cross-sections: [0.0, 1e-20, 9e-21, 7e-21, 5.4e-21, 3.2e-21, 2.7e-21, 1.7e-21, 1.09e-21, - 8e-22, 5.8e-22, 4.2e-22, 3.3e-22, 2.4e-22, 1.6e-22, 1.2e-22, 9e-23] + collision: phelps_O2_dissociation_O+O_8.4 duplicate: true -- equation: O2 + e => e + O + O + +- equation: e + O2 => e + O + O type: electron-collision-plasma - energy-levels: [10.0, 20.0, 30.0, 40.0, 50.0, 60.0, 70.0, 80.0, 100.0, 120.0, 150.0, - 170.0, 200.0, 300.0, 500.0, 700.0, 1000.0, 1500.0] - cross-sections: [0.0, 1.3e-22, 2.6e-22, 4e-22, 5e-22, 6e-22, 6.5e-22, 7e-22, 7e-22, - 5e-22, 4e-22, 3.5e-22, 3e-22, 2e-22, 1.2e-22, 8e-23, 5e-23, 0.0] + collision: phelps_O2_dissociation_O+O_10.0 duplicate: true -- equation: O2 + e => e + e + O2+ - type: electron-collision-plasma - energy-levels: [12.06, 13.0, 18.0, 28.0, 38.0, 48.0, 58.0, 68.0, 78.0, 88.0, 100.0, - 150.0, 200.0, 300.0, 500.0, 700.0, 1000.0, 1500.0, 2000.0, 3000.0, 5000.0, 7000.0, - 10000.0] - cross-sections: [0.0, 2.3e-22, 2e-21, 7.4e-21, 1.32e-20, 1.8e-20, 2.1e-20, 2.33e-20, - 2.5e-20, 2.6e-20, 2.7e-20, 2.7e-20, 2.5e-20, 2.17e-20, 1.66e-20, 1.35e-20, 1.04e-20, - 7.6e-21, 6e-21, 4.2e-21, 2.7e-21, 2e-21, 1.4e-21] - -- equation: H2O + e => e + H2O - type: electron-collision-plasma - energy-levels: [0.0, 0.03058, 0.03404, 0.03748, 0.04274, 0.04757, 0.0517, 0.05618, - 0.06322, 0.07209, 0.0842, 0.09476, 0.11068, 0.12787, 0.14391, 0.16409, 0.18266, - 0.21335, 0.24274, 0.27377, 0.31561, 0.34296, 0.42496, 0.50182, 0.60042, 0.70902, - 0.83725, 0.9673, 1.10296, 1.28547, 1.44982, 1.61386, 1.84021, 2.09831, 2.41892, - 2.78852, 3.25706, 3.84616, 4.3856, 4.88181, 5.43416, 6.11552, 6.97325, 7.86479, - 9.16619, 10.20329, 11.78805, 13.92016, 16.25909, 18.5395, 21.37223, 25.23783, - 32.38585, 39.17489, 48.54121, 59.49264, 70.25308, 80.98736, 92.34619, 109.2877, - 121.6529, 148.7734, 167.4275, 190.9099, 225.9335, 266.7981, 318.5188, 372.0378, - 419.6031, 472.2155, 544.3674, 605.9593, 651.32, 717.1263, 787.8561, 867.4574, - 953.0142, 1024.355] - cross-sections: [8.53272e-18, 8.53272e-18, 7.60881e-18, 6.80492e-18, 5.99719e-18, - 5.36357e-18, 4.79689e-18, 4.29008e-18, 3.82556e-18, 3.26424e-18, 2.86835e-18, - 2.44748e-18, 2.05187e-18, 1.77671e-18, 1.53846e-18, 1.31272e-18, 1.1914e-18, 1.01659e-18, - 8.64884e-19, 7.87264e-19, 6.48476e-19, 5.79962e-19, 4.72137e-19, 3.83231e-19, - 3.0653e-19, 2.4446e-19, 1.92681e-19, 1.56398e-19, 1.29206e-19, 1.04875e-19, 9.2427e-20, - 8.24192e-20, 7.37114e-20, 6.70961e-20, 6.17966e-20, 6.00072e-20, 6.08953e-20, - 6.38267e-20, 6.70961e-20, 7.13669e-20, 7.50225e-20, 8.00326e-20, 8.51268e-20, - 9.08117e-20, 9.2427e-20, 9.3795e-20, 9.2427e-20, 8.94872e-20, 8.38852e-20, 8.12172e-20, - 7.50225e-20, 6.38267e-20, 5.19603e-20, 4.28001e-20, 3.20908e-20, 2.48516e-20, - 1.95878e-20, 1.4904e-20, 1.20975e-20, 9.84836e-21, 8.5277e-21, 6.82093e-21, 5.80303e-21, - 5.02485e-21, 4.21263e-21, 3.48019e-21, 2.82485e-21, 2.29291e-21, 1.98544e-21, - 1.69412e-21, 1.37511e-21, 1.15283e-21, 1.01599e-21, 9.08651e-22, 7.61776e-22, - 6.59623e-22, 5.79621e-22, 5.27603e-22] -- equation: H2O + e => e + e + H2O+ - type: electron-collision-plasma - energy-levels: [0.0, 13.76, 14.19557, 15.10724, 16.07746, 16.58569, 17.10999, 17.65086, - 18.20882, 19.9908, 21.322, 22.69134, 24.912, 27.34998, 31.04466, 35.1602, 38.6011, - 46.52608, 52.81124, 65.6658, 84.41773, 101.7491, 122.9115, 162.6439, 222.5176, - 295.1039, 366.9338, 471.7177, 605.0777, 730.9258, 853.9923, 967.2048] - cross-sections: [0.0, 0.0, 5.11822e-22, 7.14142e-22, 9.1955e-22, 1.28686e-21, 1.5847e-21, - 2.03445e-21, 2.61962e-21, 3.50607e-21, 4.15379e-21, 5.33266e-21, 6.58645e-21, - 8.45572e-21, 1.04128e-20, 1.34078e-20, 1.51917e-20, 1.7213e-20, 1.79448e-20, 2.0393e-20, - 2.0393e-20, 2.0393e-20, 2.0393e-20, 1.87078e-20, 1.7213e-20, 1.51917e-20, 1.2861e-20, - 1.18334e-20, 9.58076e-21, 8.45572e-21, 7.15843e-21, 6.29907e-21] - -- equation: CO2 + e => e + CO2 - type: electron-collision-plasma - energy-levels: [0.0, 0.001, 0.002, 0.004, 0.01, 0.02, 0.04, 0.06, 0.08, 0.1, 0.12, - 0.14, 0.15, 0.17, 0.2, 0.3, 0.4, 0.5, 0.7, 0.9, 1.0, 1.2, 1.3, 1.4, 1.5, 1.6, - 1.7, 1.8, 2.0, 2.5, 3.0, 3.1, 3.2, 3.3, 3.4, 3.5, 3.6, 3.7, 3.8, 3.9, 4.0, 4.3, - 4.5, 5.0, 5.2, 5.6, 5.8, 6.0, 6.5, 7.0, 8.0, 9.0, 10.0, 11.0, 12.0, 13.5, 15.0, - 17.0, 20.0, 25.0, 40.0, 50.0, 70.0, 100.0, 150.0, 200.0, 500.0, 1000.0] - cross-sections: [6e-18, 5.4e-18, 3.87e-18, 2.7e-18, 1.7e-18, 1.19e-18, 8.4e-19, - 6.8e-19, 5.8e-19, 5.2e-19, 4.6e-19, 4.15e-19, 4e-19, 3.6e-19, 3.1e-19, 2.03e-19, - 1.43e-19, 1.09e-19, 7.5e-20, 6.05e-20, 5.55e-20, 5.02e-20, 4.9e-20, 4.88e-20, - 4.83e-20, 4.83e-20, 4.85e-20, 4.9e-20, 5.1e-20, 5.9e-20, 8.3e-20, 8.6e-20, 8.9e-20, - 9.2e-20, 9.5e-20, 9.7e-20, 9.8e-20, 9.8e-20, 9.7e-20, 9.6e-20, 9.5e-20, 8.9e-20, - 8.3e-20, 7.5e-20, 7.3e-20, 7e-20, 6.95e-20, 7e-20, 7.1e-20, 7.25e-20, 7.8e-20, - 8.45e-20, 9.2e-20, 9.75e-20, 1e-19, 1.01e-19, 1e-19, 9.6e-20, 8.9e-20, 7.75e-20, - 5.85e-20, 5.1e-20, 3.82e-20, 2.6e-20, 1.52e-20, 1.07e-20, 3.5e-21, 1.42e-21] -- equation: CO2 + e => e + e + CO2+ + +- equation: e + O2 => e + e + O2+ type: electron-collision-plasma - energy-levels: [13.7, 14.0, 14.5, 15.0, 16.0, 18.0, 20.0, 22.0, 24.0, 26.0, 28.0, - 30.0, 34.0, 40.0, 45.0, 50.0, 60.0, 70.0, 80.0, 90.0, 100.0, 130.0, 140.0, 150.0, - 180.0, 200.0, 250.0, 300.0, 400.0, 500.0, 600.0, 700.0, 800.0, 900.0, 1000.0, - 9000.0] - cross-sections: [0.0, 2e-22, 5.6e-22, 9.7e-22, 1.75e-21, 3.4e-21, 5e-21, 6.8e-21, - 9e-21, 1.11e-20, 1.32e-20, 1.5e-20, 1.77e-20, 2.11e-20, 2.35e-20, 2.56e-20, 2.92e-20, - 3.07e-20, 3.17e-20, 3.24e-20, 3.26e-20, 3.25e-20, 3.24e-20, 3.23e-20, 3.18e-20, - 3.13e-20, 3.02e-20, 2.8e-20, 2.4e-20, 2.15e-20, 1.93e-20, 1.73e-20, 1.6e-20, 1.47e-20, - 1.4e-20, 0.0] - -- equation: CH4 + e => e + CH4 + collision: phelps_O2_ionization_O2^+_12.06 + +- equation: e + H2O => e + e + H2O+ type: electron-collision-plasma - energy-levels: [0.0, 0.01, 0.01208, 0.01409, 0.01702, 0.02098, 0.02644, 0.03484, - 0.04166, 0.05135, 0.06064, 0.07148, 0.0834, 0.09851, 0.11494, 0.13882, 0.16198, - 0.19326, 0.22052, 0.24358, 0.27235, 0.30762, 0.351, 0.40051, 0.46259, 0.53975, - 0.62978, 0.74383, 0.92803, 1.10727, 1.36474, 1.70269, 2.12433, 2.39946, 2.83399, - 3.38135, 4.03444, 5.19964, 6.34399, 8.36083, 10.30497, 13.44393, 18.33999, 23.35073, - 29.49006, 37.54714, 45.81062, 57.15473, 70.58796, 87.88912, 110.9968, 146.2842, - 180.2994, 224.9471, 283.5137, 369.8738, 455.88, 543.93, 656.9384, 742.0208, 827.9771, - 905.3268, 956.3272] - cross-sections: [2.06383e-19, 2.06383e-19, 1.86094e-19, 1.65686e-19, 1.39635e-19, - 1.14736e-19, 9.4276e-20, 7.68131e-20, 6.52849e-20, 5.13162e-20, 4.31565e-20, 3.39225e-20, - 2.63285e-20, 2.06952e-20, 1.68262e-20, 1.35368e-20, 1.13843e-20, 9.59438e-21, - 8.45252e-21, 7.3528e-21, 6.56032e-21, 6.19671e-21, 6.19671e-21, 6.62996e-21, 7.44656e-21, - 9.37407e-21, 1.18005e-20, 1.53655e-20, 2.06952e-20, 2.66643e-20, 3.6371e-20, 5.13162e-20, - 7.41042e-20, 9.01863e-20, 1.13531e-19, 1.36429e-19, 1.51303e-19, 1.60181e-19, - 1.60181e-19, 1.51303e-19, 1.36429e-19, 1.14736e-19, 8.70058e-20, 6.83897e-20, - 5.25223e-20, 3.89139e-20, 3.02664e-20, 2.29515e-20, 1.76264e-20, 1.36805e-20, - 1.05064e-20, 7.70248e-21, 6.2625e-21, 5.03823e-21, 4.00227e-21, 3.10631e-21, 2.49906e-21, - 2.05342e-21, 1.66953e-21, 1.45539e-21, 1.26871e-21, 1.14399e-21, 1.05577e-21] -- equation: CH4 + e => e + CH3 + H + collision: hayashi_H2O_ionization_H2O^+_13.76 + +- equation: e + CO2 => e + e + CO2+ type: electron-collision-plasma - energy-levels: [7.9, 7.90821, 8.08679, 8.1859, 8.26942, 8.37076, 8.45616, 8.54244, - 8.73535, 8.8424, 8.93262, 9.13434, 9.34062, 9.55155, 9.76726, 9.98783, 10.19267, - 10.55058, 11.03248, 11.39673, 11.91728, 12.43633, 13.00437, 13.90544, 15.02064, - 16.06142, 16.76097, 18.32707, 20.45048, 22.8663, 27.28362, 32.8864, 38.84312, - 43.87476, 52.8846, 74.53031, 95.08989, 113.4594, 134.0103, 163.5094, 188.4777, - 217.7004, 257.1325, 286.9245, 324.092, 386.7002, 451.2133, 521.1721, 615.5719, - 695.3117, 801.488, 885.318, 968.0396] - cross-sections: [0.0, 1.06974e-22, 1.28491e-22, 1.61659e-22, 2.47406e-22, 2.93439e-22, - 3.48771e-22, 5.03192e-22, 5.90564e-22, 7.25985e-22, 8.9246e-22, 1.07198e-21, 1.34868e-21, - 1.65795e-21, 2.05971e-21, 2.50549e-21, 3.08002e-21, 3.73874e-21, 4.87533e-21, - 6.19874e-21, 8.25526e-21, 1.06297e-20, 1.30396e-20, 1.46415e-20, 1.64055e-20, - 1.79989e-20, 1.99562e-20, 2.31758e-20, 2.59681e-20, 2.7488e-20, 2.84902e-20, 2.72e-20, - 2.51074e-20, 2.36692e-20, 2.09028e-20, 1.60297e-20, 1.35151e-20, 1.20365e-20, - 1.03862e-20, 8.94329e-21, 7.96484e-21, 7.27505e-21, 6.34406e-21, 5.78244e-21, - 5.21532e-21, 4.54791e-21, 4.00791e-21, 3.49501e-21, 3.08002e-21, 2.77794e-21, - 2.50549e-21, 2.33723e-21, 2.208e-21] -- equation: CH4 + e => e + e + CH4+ + collision: hayashi_CO2_ionization_CO2^+_13.7 + +- equation: e + CH4 => e + CH3 + H type: electron-collision-plasma - energy-levels: [12.9, 13.19695, 13.33182, 13.4955, 13.77277, 13.94186, 14.25727, - 14.40299, 14.72883, 15.06204, 15.56021, 16.27222, 17.0168, 18.79994, 21.23981, - 22.66805, 25.04337, 27.38768, 29.58817, 32.35792, 35.31504, 39.0156, 45.07628, - 50.92631, 58.71766, 70.94303, 86.58983, 104.4058, 120.6242, 140.7863, 162.656, - 185.6438, 212.3117, 236.9566, 267.709, 295.7614, 330.765, 372.9327, 421.3322, - 471.1971, 514.2588, 580.9997, 656.4023, 725.1848, 791.4579, 865.5462, 914.4029, - 987.8718] - cross-sections: [0.0, 1.92453e-22, 2.45358e-22, 3.97115e-22, 5.17086e-22, 6.81888e-22, - 8.58391e-22, 1.10598e-21, 1.66953e-21, 2.12848e-21, 2.93414e-21, 3.96023e-21, - 6.05442e-21, 7.52561e-21, 1.11229e-20, 1.30594e-20, 1.55286e-20, 1.78135e-20, - 1.97556e-20, 2.14064e-20, 2.37403e-20, 2.51864e-20, 2.69473e-20, 2.85889e-20, - 2.95714e-20, 3.02664e-20, 3.05877e-20, 3.02664e-20, 2.9199e-20, 2.79324e-20, 2.66643e-20, - 2.54538e-20, 2.4043e-20, 2.27104e-20, 2.16794e-20, 2.06952e-20, 1.93428e-20, 1.78135e-20, - 1.66494e-20, 1.58936e-20, 1.50127e-20, 1.3855e-20, 1.29223e-20, 1.20524e-20, 1.13843e-20, - 1.08675e-20, 1.03961e-20, 1.00295e-20] - -- equation: CO + e => e + CO + collision: hayashi_CH4_dissociation_CH3+H_7.9 + +- equation: e + CH4 => e + e + CH4+ type: electron-collision-plasma - energy-levels: [0.0, 0.001, 0.002, 0.003, 0.005, 0.007, 0.0085, 0.01, 0.015, 0.02, - 0.03, 0.04, 0.05, 0.07, 0.1, 0.12, 0.15, 0.17, 0.2, 0.25, 0.3, 0.35, 0.4, 0.5, - 0.7, 1.0, 1.2, 1.3, 1.5, 1.7, 1.9, 2.1, 2.2, 2.5, 2.8, 3.0, 3.3, 3.6, 4.0, 4.5, - 5.0, 6.0, 7.0, 8.0, 10.0, 12.0, 15.0, 17.0, 20.0, 25.0, 30.0, 50.0, 75.0, 100.0, - 150.0, 200.0, 300.0, 500.0, 700.0, 1000.0] - cross-sections: [6e-19, 4e-19, 2.5e-19, 1.77e-19, 1.23e-19, 9.8e-20, 8.6e-20, 7.8e-20, - 6.5e-20, 5.9e-20, 5.4e-20, 5.2e-20, 5.4e-20, 6.1e-20, 7.3e-20, 7.7e-20, 8.8e-20, - 9.3e-20, 1e-19, 1.12e-19, 1.21e-19, 1.3e-19, 1.385e-19, 1.54e-19, 1.65e-19, 1.85e-19, - 2.8e-19, 3.7e-19, 4.2e-19, 4e-19, 3.2e-19, 2.35e-19, 2.15e-19, 1.75e-19, 1.6e-19, - 1.54e-19, 1.46e-19, 1.42e-19, 1.38e-19, 1.33e-19, 1.29e-19, 1.23e-19, 1.18e-19, - 1.13e-19, 1.06e-19, 1.04e-19, 1.02e-19, 1.01e-19, 9.8e-20, 9.1e-20, 8.6e-20, 7.1e-20, - 6.1e-20, 5.5e-20, 4.9e-20, 4.2e-20, 3.3e-20, 2.44e-20, 1.96e-20, 1.55e-20] + collision: hayashi_CH4_ionization_CH4^+_12.9 + + +electron-collisions: +- name: siglo_N2_elastic_N2_0.0 + target: N2 + product: N2 + energy-levels: [0.0, 0.01, 0.015, 0.02, 0.03, 0.04, 0.05, 0.07, 0.1, 0.12, 0.15, 0.17, 0.2, 0.25, 0.3, 0.35, 0.4, 0.5, 0.7, 1.0, 1.2, 1.3, 1.5, 1.7, 1.9, 2.1, 2.2, 2.5, 2.8, 3.0, 3.3, 3.6, 4.0, 4.5, 5.0, 6.0, 7.0, 8.0, 10.0, 12.0, 15.0, 17.0, 20.0, 25.0, 30.0, 50.0, 75.0, 100.0, 150.0, 200.0, 300.0, 500.0, 700.0, 1000.0] + cross-sections: [1.1e-20, 2.19e-20, 2.55e-20, 2.85e-20, 3.38e-20, 3.82e-20, 4.3e-20, 5.08e-20, 5.92e-20, 6.42e-20, 7.08e-20, 7.38e-20, 7.88e-20, 8.48e-20, 8.98e-20, 9.36e-20, 9.67e-20, 9.87e-20, 9.97e-20, 9.96e-20, 1.034e-19, 1.092e-19, 1.187e-19, 1.347e-19, 1.641e-19, 1.685e-19, 1.802e-19, 1.792e-19, 2.1e-19, 1.72e-19, 1.53e-19, 1.396e-19, 1.242e-19, 1.119e-19, 1.086e-19, 1.036e-19, 1.0e-19, 1.02e-19, 9.9e-20, 9.5e-20, 8.7e-20, 8.26e-20, 7.6e-20, 6.7e-20, 5.9e-20, 3.8e-20, 2.56e-20, 1.8e-20, 1.13e-20, 8.0e-21, 4.8e-21, 2.3e-21, 1.43e-21, 7.0e-22] + threshold: 0.0 + kind: elastic # as mentioned in the SIGLO database files from LXCat + +- name: siglo_N2_excitation_N2(v1)_1.6 + target: N2 + product: N2(v1) + energy-levels: [1.6, 1.65, 1.7, 1.8, 1.9, 2.0, 2.1, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.75, 2.8, 2.9, 3.0, 3.1, 3.2, 3.3, 3.4, 3.5, 3.6, 4.0] + cross-sections: [0.0, 2.7e-21, 3.15e-21, 5.4e-21, 1.485e-20, 4.8e-20, 2.565e-20, 1.2e-20, 4.5e-20, 2.76e-20, 1.59e-20, 3.15e-20, 1.545e-20, 6.0e-21, 1.35e-20, 5.25e-21, 8.7e-21, 1.17e-20, 8.55e-21, 6.6e-21, 6.0e-21, 5.85e-21, 5.7e-21, 0.0] + threshold: 1.6 + kind: excitation + +- name: siglo_N2_excitation_N2(v2)_1.7 + target: N2 + product: N2(v2) + energy-levels: [1.7, 1.8, 1.9, 2.0, 2.1, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.75, 2.8, 2.9, 3.0, 3.1, 3.2, 3.3, 3.4, 3.5, 3.6] + cross-sections: [0.0, 1.5e-22, 6.3e-21, 1.935e-20, 3.3e-20, 1.47e-20, 5.4e-21, 2.115e-20, 3.0e-20, 5.4e-21, 1.05e-20, 1.725e-20, 1.275e-20, 3.3e-21, 9.0e-21, 6.45e-21, 3.75e-21, 3.45e-21, 3.0e-21, 2.13e-21, 0.0] + threshold: 1.7 + kind: excitation + +- name: siglo_N2_excitation_N2(v3)_1.9 + target: N2 + product: N2(v3) + energy-levels: [1.9, 2.0, 2.1, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.75, 2.8, 2.9, 3.0, 3.1, 3.2, 3.3, 3.4] + cross-sections: [0.0, 9.6e-21, 2.055e-20, 2.7e-20, 1.695e-20, 7.5e-22, 9.6e-21, 1.47e-20, 4.5e-21, 9.6e-21, 5.4e-21, 8.55e-21, 4.05e-21, 2.82e-21, 2.91e-21, 6.15e-22, 0.0] + threshold: 1.9 + kind: excitation + +- name: siglo_N2_excitation_N2(v4)_2.0 + target: N2 + product: N2(v4) + energy-levels: [2.0, 2.1, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.75, 2.8, 2.9, 3.0, 3.1, 3.2, 3.3] + cross-sections: [0.0, 2.025e-21, 1.515e-20, 2.385e-20, 1.44e-20, 5.55e-21, 8.25e-22, 1.2e-20, 1.095e-20, 6.75e-21, 3.0e-22, 3.3e-21, 3.15e-21, 6.0e-22, 0.0] + threshold: 2.0 + kind: excitation + +- name: siglo_N2_excitation_N2(v5)_2.1 + target: N2 + product: N2(v5) + energy-levels: [2.1, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.75, 2.8, 2.9, 3.0, 3.1, 3.2, 3.3, 3.4] + cross-sections: [0.0, 8.25e-21, 1.23e-20, 1.53e-20, 1.44e-20, 3.45e-21, 2.25e-22, 3.45e-21, 5.4e-21, 6.6e-21, 2.175e-21, 1.05e-21, 3.15e-21, 1.035e-21, 0.0] + threshold: 2.1 + kind: excitation + +- name: siglo_N2_excitation_N2(v6)_2.2 + target: N2 + product: N2(v6) + energy-levels: [2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.75, 2.8, 2.9, 3.0, 3.1, 3.2] + cross-sections: [0.0, 6.3e-23, 1.125e-20, 1.74e-20, 1.38e-20, 7.8e-21, 4.5e-21, 3.15e-21, 2.46e-21, 4.8e-21, 1.635e-21, 0.0] + threshold: 2.2 + kind: excitation + +- name: siglo_N2_excitation_N2(v7)_2.3 + target: N2 + product: N2(v7) + energy-levels: [2.3, 2.4, 2.5, 2.6, 2.7, 2.75, 2.8, 2.9, 3.0, 3.1, 3.2, 3.3, 3.4, 3.5] + cross-sections: [0.0, 1.26e-22, 3.9e-21, 6.6e-21, 9.6e-21, 7.95e-21, 6.0e-21, 1.8e-21, 6.3e-23, 1.92e-21, 2.04e-21, 7.8e-22, 1.89e-22, 0.0] + threshold: 2.3 + kind: excitation + +- name: siglo_N2_excitation_N2(v8)_2.5 + target: N2 + product: N2(v8) + energy-levels: [2.5, 2.6, 2.7, 2.75, 2.8, 2.9, 3.0, 3.1, 3.2, 3.3, 3.4, 3.5] + cross-sections: [0.0, 1.89e-22, 3.6e-21, 3.6e-21, 3.3e-21, 3.45e-21, 2.64e-21, 3.75e-22, 6.3e-23, 1.545e-21, 2.52e-22, 0.0] + threshold: 2.5 + kind: excitation + +- name: siglo_N2_excitation_N2(A)_6.17 + target: N2 + product: N2(A) + energy-levels: [6.17, 7.0, 7.8, 8.5, 9.0, 10.0, 11.0, 12.0, 13.0, 14.0, 16.0, 17.0, 18.0, 20.0, 22.0, 24.0, 26.0, 30.0, 34.0, 40.0, 50.0, 70.0, 150.0] + cross-sections: [0.0, 1.0e-23, 2.8e-23, 4.3e-23, 5.2e-23, 8.2e-23, 1.0e-22, 1.2e-22, 1.3e-22, 1.4e-22, 1.5e-22, 1.5e-22, 1.4e-22, 1.2e-22, 1.0e-22, 8.9e-23, 7.6e-23, 5.9e-23, 4.9e-23, 3.9e-23, 3.4e-23, 7.0e-24, 0.0] + threshold: 6.17 + kind: excitation + +- name: siglo_N2_excitation_N2(A)_7.0 + target: N2 + product: N2(A) + energy-levels: [7.0, 7.3, 7.8, 8.5, 9.0, 10.0, 11.0, 12.0, 13.0, 14.0, 16.0, 17.0, 18.0, 20.0, 22.0, 24.0, 26.0, 30.0, 34.0, 40.0, 50.0, 70.0, 150.0] + cross-sections: [0.0, 2.0e-23, 5.0e-23, 1.5e-22, 2.2e-22, 3.4e-22, 4.3e-22, 5.0e-22, 5.5e-22, 6.0e-22, 6.5e-22, 6.5e-22, 6.2e-22, 5.3e-22, 4.5e-22, 3.8e-22, 3.3e-22, 2.5e-22, 2.1e-22, 1.7e-22, 1.4e-22, 2.9e-23, 0.0] + threshold: 7.0 + kind: excitation + +- name: siglo_N2_excitation_N2(B)_7.35 + target: N2 + product: N2(B) + energy-levels: [7.35, 8.0, 9.0, 10.0, 11.0, 12.0, 13.0, 14.0, 15.0, 16.0, 17.0, 18.0, 20.0, 22.0, 26.0, 30.0, 34.0, 40.0, 50.0, 70.0, 150.0] + cross-sections: [0.0, 3.62e-22, 9.38e-22, 1.508e-21, 1.863e-21, 2.003e-21, 1.99e-21, 1.816e-21, 1.615e-21, 1.447e-21, 1.307e-21, 1.199e-21, 1.112e-21, 9.51e-22, 8.04e-22, 6.77e-22, 5.63e-22, 4.29e-22, 2.68e-22, 6.7e-23, 0.0] + threshold: 7.35 + kind: excitation + +- name: siglo_N2_excitation_N2(B)_7.36 + target: N2 + product: N2(B) + energy-levels: [7.36, 8.0, 9.0, 10.0, 11.0, 12.0, 14.0, 15.0, 16.0, 17.0, 18.0, 20.0, 22.0, 24.0, 26.0, 28.0, 30.0, 34.0, 40.0, 50.0, 70.0, 100.0, 150.0] + cross-sections: [0.0, 1.8e-23, 4.96e-22, 8.04e-22, 1.112e-21, 1.427e-21, 2.05e-21, 2.352e-21, 2.546e-21, 2.519e-21, 2.345e-21, 1.776e-21, 1.32e-21, 1.025e-21, 8.44e-22, 7.24e-22, 6.3e-22, 4.96e-22, 3.48e-22, 2.01e-22, 1.01e-22, 4.7e-23, 0.0] + threshold: 7.36 + kind: excitation + +- name: siglo_N2_excitation_N2(A)_7.8 + target: N2 + product: N2(A) + energy-levels: [7.8, 8.1, 8.5, 8.7, 9.0, 10.0, 11.0, 12.0, 13.0, 14.0, 16.0, 17.0, 18.0, 20.0, 22.0, 24.0, 26.0, 30.0, 34.0, 40.0, 50.0, 70.0, 150.0] + cross-sections: [0.0, 1.5e-23, 4.0e-23, 7.0e-23, 1.1e-22, 2.9e-22, 4.4e-22, 5.1e-22, 5.6e-22, 6.0e-22, 6.6e-22, 6.7e-22, 6.3e-22, 5.4e-22, 4.6e-22, 3.9e-22, 3.3e-22, 2.6e-22, 2.1e-22, 1.7e-22, 1.5e-22, 3.0e-23, 0.0] + threshold: 7.8 + kind: excitation + +- name: siglo_N2_excitation_N2(B)_8.16 + target: N2 + product: N2(B) + energy-levels: [8.16, 9.0, 10.0, 11.0, 12.0, 13.0, 14.0, 15.0, 16.0, 17.0, 18.0, 19.0, 20.0, 22.0, 26.0, 30.0, 34.0, 40.0, 50.0, 70.0, 150.0] + cross-sections: [0.0, 1.07e-22, 2.35e-22, 3.69e-22, 4.96e-22, 6.3e-22, 7.57e-22, 8.38e-22, 7.64e-22, 6.16e-22, 4.89e-22, 4.09e-22, 3.62e-22, 3.15e-22, 2.68e-22, 2.28e-22, 1.94e-22, 1.61e-22, 1.27e-22, 6.7e-23, 0.0] + threshold: 8.16 + kind: excitation + +- name: siglo_N2_excitation_N2(a')_8.4 + target: N2 + product: N2(a') + energy-levels: [8.4, 9.0, 11.0, 13.0, 14.0, 15.0, 16.0, 17.0, 18.0, 19.0, 20.0, 24.0, 30.0, 40.0, 50.0, 70.0, 150.0, 500.0] + cross-sections: [0.0, 6.7e-23, 3.02e-22, 5.36e-22, 6.43e-22, 6.97e-22, 5.7e-22, 4.29e-22, 3.48e-22, 3.08e-22, 2.75e-22, 2.01e-22, 1.54e-22, 1.24e-22, 1.21e-22, 1.01e-22, 6.7e-23, 0.0] + threshold: 8.4 + kind: excitation + +- name: siglo_N2_excitation_N2(a')_8.55 + target: N2 + product: N2(a') + energy-levels: [8.55, 9.0, 14.0, 15.0, 16.0, 17.0, 18.0, 19.0, 20.0, 24.0, 26.0, 30.0, 40.0, 50.0, 70.0, 100.0, 150.0, 200.0, 250.0, 300.0, 500.0, 700.0, 1000.0] + cross-sections: [0.0, 1.27e-22, 1.474e-21, 1.715e-21, 1.916e-21, 2.023e-21, 1.99e-21, 1.923e-21, 1.849e-21, 1.621e-21, 1.528e-21, 1.367e-21, 1.065e-21, 8.51e-22, 6.03e-22, 4.02e-22, 2.68e-22, 2.01e-22, 1.61e-22, 1.34e-22, 8.2e-23, 6.0e-23, 4.2e-23] + threshold: 8.55 + kind: excitation + +- name: siglo_N2_excitation_N2(a')_8.89 + target: N2 + product: N2(a') + energy-levels: [8.89, 9.0, 10.0, 11.0, 12.0, 13.0, 14.0, 15.0, 16.0, 17.0, 18.0, 20.0, 22.0, 30.0, 38.0, 50.0, 150.0] + cross-sections: [0.0, 1.3e-23, 2.61e-22, 4.76e-22, 6.63e-22, 7.84e-22, 7.71e-22, 6.7e-22, 5.43e-22, 4.42e-22, 3.75e-22, 2.88e-22, 2.41e-22, 1.54e-22, 9.4e-23, 4.7e-23, 0.0] + threshold: 8.89 + kind: excitation + +- name: siglo_N2_excitation_N2(C)_11.03 + target: N2 + product: N2(C) + energy-levels: [11.03, 11.5, 12.0, 12.5, 13.0, 13.5, 13.8, 14.0, 14.2, 14.5, 15.0, 16.0, 17.0, 18.0, 19.0, 20.0, 22.0, 24.0, 26.0, 28.0, 30.0, 36.0, 40.0, 50.0, 70.0, 100.0, 150.0] + cross-sections: [0.0, 4.05e-22, 9.3e-22, 1.965e-21, 4.35e-21, 7.36e-21, 9.3e-21, 9.75e-21, 9.6e-21, 9.45e-21, 8.25e-21, 6.45e-21, 5.25e-21, 4.5e-21, 4.05e-21, 3.75e-21, 3.15e-21, 2.655e-21, 2.25e-21, 2.085e-21, 1.665e-21, 1.17e-21, 9.45e-22, 5.85e-22, 2.25e-22, 2.3e-23, 0.0] + threshold: 11.03 + kind: excitation + +- name: siglo_N2_excitation_N2(C)_11.87 + target: N2 + product: N2(C) + energy-levels: [11.87, 11.92, 12.7, 17.0, 19.0, 20.0, 22.0, 24.0, 26.0, 28.0, 30.0, 32.0, 40.0, 50.0, 150.0] + cross-sections: [0.0, 4.96e-22, 7.0e-24, 3.4e-23, 4.2e-23, 4.7e-23, 5.2e-23, 5.4e-23, 5.4e-23, 4.4e-23, 3.4e-23, 2.7e-23, 1.2e-23, 5.0e-24, 0.0] + threshold: 11.87 + kind: excitation + +- name: siglo_N2_ionization_N2^+_15.6 + target: N2 + product: N2^+ + energy-levels: [15.6, 16.0, 16.5, 17.0, 17.5, 18.0, 18.5, 19.0, 19.5, 20.0, 21.0, 22.0, 23.0, 25.0, 30.0, 34.0, 45.0, 60.0, 75.0, 100.0, 150.0, 200.0, 300.0, 500.0, 700.0, 1000.0] + cross-sections: [0.0, 2.1e-22, 4.6e-22, 7.1e-22, 9.8e-22, 1.29e-21, 1.63e-21, 1.98e-21, 2.29e-21, 2.69e-21, 3.42e-21, 4.16e-21, 4.9e-21, 6.37e-21, 1.03e-20, 1.26e-20, 1.77e-20, 2.17e-20, 2.38e-20, 2.52e-20, 2.44e-20, 2.26e-20, 1.91e-20, 1.45e-20, 1.16e-20, 9.2e-21] + threshold: 15.6 + kind: ionization + +- name: phelps_O2_effective_O2_0.0 + target: O2 + product: O2 + energy-levels: [0.0, 0.001, 0.002, 0.003, 0.005, 0.007, 0.0085, 0.01, 0.015, 0.02, 0.03, 0.04, 0.05, 0.07, 0.1, 0.12, 0.15, 0.17, 0.2, 0.25, 0.3, 0.35, 0.4, 0.5, 0.7, 1.0, 1.2, 1.3, 1.5, 1.7, 1.9, 2.1, 2.2, 2.5, 2.8, 3.0, 3.3, 3.6, 4.0, 4.5, 5.0, 6.0, 7.0, 8.0, 10.0, 12.0, 15.0, 17.0, 20.0, 25.0, 30.0, 50.0, 75.0, 100.0, 150.0, 200.0, 300.0, 500.0, 700.0, 1000.0, 1500.0, 2000.0, 3000.0, 5000.0, 7000.0, 10000.0] + cross-sections: [3.5e-21, 3.5e-21, 3.6e-21, 4.0e-21, 5.0e-21, 5.8e-21, 6.4e-21, 7.0e-21, 8.7e-21, 9.9e-21, 1.24e-20, 1.44e-20, 1.6e-20, 2.1e-20, 2.5e-20, 2.8e-20, 3.1e-20, 3.3e-20, 3.6e-20, 4.1e-20, 4.5e-20, 4.7e-20, 5.2e-20, 5.7e-20, 6.1e-20, 7.2e-20, 7.9e-20, 7.9e-20, 7.6e-20, 7.3e-20, 6.9e-20, 6.6e-20, 6.5e-20, 6.1e-20, 5.8e-20, 5.7e-20, 5.5e-20, 5.45e-20, 5.5e-20, 5.55e-20, 5.6e-20, 6.0e-20, 6.6e-20, 7.1e-20, 8.0e-20, 8.5e-20, 8.8e-20, 8.7e-20, 8.6e-20, 8.2e-20, 8.0e-20, 7.7e-20, 6.8e-20, 6.5e-20, 6.7e-20, 6.0e-20, 4.9e-20, 3.6e-20, 2.9e-20, 2.12e-20, 1.48e-20, 1.14e-20, 7.9e-21, 5.1e-21, 3.8e-21, 2.8e-21] + threshold: 0.0 + kind: effective # as mentioned on the Phelps database. + +- name: phelps_O2_dissociation_O+O_6.0 + target: O2 + product: O+O + energy-levels: [6.0, 7.0, 7.8, 9.0, 10.0, 12.0, 15.0, 17.0, 20.0, 45.0, 100.0] + cross-sections: [0.0, 1.5e-21, 2.3e-21, 2.3e-21, 2.1e-21, 1.65e-21, 1.05e-21, 6.5e-22, 4.75e-22, 1.9e-22, 0.0] + threshold: 6.0 + kind: excitation + +- name: phelps_O2_dissociation_O+O_8.4 + target: O2 + product: O+O + energy-levels: [8.4, 9.4, 30.0, 50.0, 100.0, 150.0, 200.0, 300.0, 500.0, 700.0, 1000.0, 1500.0, 2000.0, 3000.0, 5000.0, 7000.0, 10000.0] + cross-sections: [0.0, 1.0e-20, 9.0e-21, 7.0e-21, 5.4e-21, 3.2e-21, 2.7e-21, 1.7e-21, 1.09e-21, 8.0e-22, 5.8e-22, 4.2e-22, 3.3e-22, 2.4e-22, 1.6e-22, 1.2e-22, 9.0e-23] + threshold: 8.4 + kind: excitation + +- name: phelps_O2_dissociation_O+O_10.0 + target: O2 + product: O+O + energy-levels: [10.0, 20.0, 30.0, 40.0, 50.0, 60.0, 70.0, 80.0, 100.0, 120.0, 150.0, 170.0, 200.0, 300.0, 500.0, 700.0, 1000.0, 1500.0] + cross-sections: [0.0, 1.3e-22, 2.6e-22, 4.0e-22, 5.0e-22, 6.0e-22, 6.5e-22, 7.0e-22, 7.0e-22, 5.0e-22, 4.0e-22, 3.5e-22, 3.0e-22, 2.0e-22, 1.2e-22, 8.0e-23, 5.0e-23, 0.0] + threshold: 10.0 + kind: excitation + +- name: phelps_O2_ionization_O2^+_12.06 + target: O2 + product: O2^+ + energy-levels: [12.06, 13.0, 18.0, 28.0, 38.0, 48.0, 58.0, 68.0, 78.0, 88.0, 100.0, 150.0, 200.0, 300.0, 500.0, 700.0, 1000.0, 1500.0, 2000.0, 3000.0, 5000.0, 7000.0, 10000.0] + cross-sections: [0.0, 2.3e-22, 2.0e-21, 7.4e-21, 1.32e-20, 1.8e-20, 2.1e-20, 2.33e-20, 2.5e-20, 2.6e-20, 2.7e-20, 2.7e-20, 2.5e-20, 2.17e-20, 1.66e-20, 1.35e-20, 1.04e-20, 7.6e-21, 6.0e-21, 4.2e-21, 2.7e-21, 2.0e-21, 1.4e-21] + threshold: 12.06 + kind: ionization + +- name: hayashi_H2O_elastic_H2O_0.0 + target: H2O + product: H2O + energy-levels: [0.0, 0.03058, 0.03404, 0.03748, 0.04274, 0.04757, 0.0517, 0.05618, 0.06322, 0.07209, 0.0842, 0.09476, 0.11068, 0.12787, 0.14391, 0.16409, 0.18266, 0.21335, 0.24274, 0.27377, 0.31561, 0.34296, 0.42496, 0.50182, 0.60042, 0.70902, 0.83725, 0.9673, 1.10296, 1.28547, 1.44982, 1.61386, 1.84021, 2.09831, 2.41892, 2.78852, 3.25706, 3.84616, 4.3856, 4.88181, 5.43416, 6.11552, 6.97325, 7.86479, 9.16619, 10.20329, 11.78805, 13.92016, 16.25909, 18.5395, 21.37223, 25.23783, 32.38585, 39.17489, 48.54121, 59.49264, 70.25308, 80.98736, 92.34619, 109.2877, 121.6529, 148.7734, 167.4275, 190.9099, 225.9335, 266.7981, 318.5188, 372.0378, 419.6031, 472.2155, 544.3674, 605.9593, 651.32, 717.1263, 787.8561, 867.4574, 953.0142, 1024.355] + cross-sections: [8.53272e-18, 8.53272e-18, 7.60881e-18, 6.80492e-18, 5.99719e-18, 5.36357e-18, 4.79689e-18, 4.29008e-18, 3.82556e-18, 3.26424e-18, 2.86835e-18, 2.44748e-18, 2.05187e-18, 1.77671e-18, 1.53846e-18, 1.31272e-18, 1.1914e-18, 1.01659e-18, 8.64884e-19, 7.87264e-19, 6.48476e-19, 5.79962e-19, 4.72137e-19, 3.83231e-19, 3.0653e-19, 2.4446e-19, 1.92681e-19, 1.56398e-19, 1.29206e-19, 1.04875e-19, 9.2427e-20, 8.24192e-20, 7.37114e-20, 6.70961e-20, 6.17966e-20, 6.00072e-20, 6.08953e-20, 6.38267e-20, 6.70961e-20, 7.13669e-20, 7.50225e-20, 8.00326e-20, 8.51268e-20, 9.08117e-20, 9.2427e-20, 9.3795e-20, 9.2427e-20, 8.94872e-20, 8.38852e-20, 8.12172e-20, 7.50225e-20, 6.38267e-20, 5.19603e-20, 4.28001e-20, 3.20908e-20, 2.48516e-20, 1.95878e-20, 1.4904e-20, 1.20975e-20, 9.84836e-21, 8.5277e-21, 6.82093e-21, 5.80303e-21, 5.02485e-21, 4.21263e-21, 3.48019e-21, 2.82485e-21, 2.29291e-21, 1.98544e-21, 1.69412e-21, 1.37511e-21, 1.15283e-21, 1.01599e-21, 9.08651e-22, 7.61776e-22, 6.59623e-22, 5.79621e-22, 5.27603e-22] + threshold: 0.0 + kind: elastic + +- name: hayashi_H2O_ionization_H2O^+_13.76 + target: H2O + product: H2O^+ + energy-levels: [0.0, 13.76, 14.19557, 15.10724, 16.07746, 16.58569, 17.10999, 17.65086, 18.20882, 19.9908, 21.322, 22.69134, 24.912, 27.34998, 31.04466, 35.1602, 38.6011, 46.52608, 52.81124, 65.6658, 84.41773, 101.7491, 122.9115, 162.6439, 222.5176, 295.1039, 366.9338, 471.7177, 605.0777, 730.9258, 853.9923, 967.2048] + cross-sections: [0.0, 0.0, 5.11822e-22, 7.14142e-22, 9.1955e-22, 1.28686e-21, 1.5847e-21, 2.03445e-21, 2.61962e-21, 3.50607e-21, 4.15379e-21, 5.33266e-21, 6.58645e-21, 8.45572e-21, 1.04128e-20, 1.34078e-20, 1.51917e-20, 1.7213e-20, 1.79448e-20, 2.0393e-20, 2.0393e-20, 2.0393e-20, 2.0393e-20, 1.87078e-20, 1.7213e-20, 1.51917e-20, 1.2861e-20, 1.18334e-20, 9.58076e-21, 8.45572e-21, 7.15843e-21, 6.29907e-21] + threshold: 13.76 + kind: ionization + +- name: hayashi_CO2_elastic_CO2_0.0 + target: CO2 + product: CO2 + energy-levels: [0.0, 0.001, 0.002, 0.004, 0.01, 0.02, 0.04, 0.06, 0.08, 0.1, 0.12, 0.14, 0.15, 0.17, 0.2, 0.3, 0.4, 0.5, 0.7, 0.9, 1.0, 1.2, 1.3, 1.4, 1.5, 1.6, 1.7, 1.8, 2.0, 2.5, 3.0, 3.1, 3.2, 3.3, 3.4, 3.5, 3.6, 3.7, 3.8, 3.9, 4.0, 4.3, 4.5, 5.0, 5.2, 5.6, 5.8, 6.0, 6.5, 7.0, 8.0, 9.0, 10.0, 11.0, 12.0, 13.5, 15.0, 17.0, 20.0, 25.0, 40.0, 50.0, 70.0, 100.0, 150.0, 200.0, 500.0, 1000.0] + cross-sections: [6.0e-18, 5.4e-18, 3.87e-18, 2.7e-18, 1.7e-18, 1.19e-18, 8.4e-19, 6.8e-19, 5.8e-19, 5.2e-19, 4.6e-19, 4.15e-19, 4.0e-19, 3.6e-19, 3.1e-19, 2.03e-19, 1.43e-19, 1.09e-19, 7.5e-20, 6.05e-20, 5.55e-20, 5.02e-20, 4.9e-20, 4.88e-20, 4.83e-20, 4.83e-20, 4.85e-20, 4.9e-20, 5.1e-20, 5.9e-20, 8.3e-20, 8.6e-20, 8.9e-20, 9.2e-20, 9.5e-20, 9.7e-20, 9.8e-20, 9.8e-20, 9.7e-20, 9.6e-20, 9.5e-20, 8.9e-20, 8.3e-20, 7.5e-20, 7.3e-20, 7.0e-20, 6.95e-20, 7.0e-20, 7.1e-20, 7.25e-20, 7.8e-20, 8.45e-20, 9.2e-20, 9.75e-20, 1.0e-19, 1.01e-19, 1.0e-19, 9.6e-20, 8.9e-20, 7.75e-20, 5.85e-20, 5.1e-20, 3.82e-20, 2.6e-20, 1.52e-20, 1.07e-20, 3.5e-21, 1.42e-21] + threshold: 0.0 + kind: elastic + +- name: hayashi_CO2_ionization_CO2^+_13.7 + target: CO2 + product: CO2^+ + energy-levels: [13.7, 14.0, 14.5, 15.0, 16.0, 18.0, 20.0, 22.0, 24.0, 26.0, 28.0, 30.0, 34.0, 40.0, 45.0, 50.0, 60.0, 70.0, 80.0, 90.0, 100.0, 130.0, 140.0, 150.0, 180.0, 200.0, 250.0, 300.0, 400.0, 500.0, 600.0, 700.0, 800.0, 900.0, 1000.0, 9000.0] + cross-sections: [0.0, 2.0e-22, 5.6e-22, 9.7e-22, 1.75e-21, 3.4e-21, 5.0e-21, 6.8e-21, 9.0e-21, 1.11e-20, 1.32e-20, 1.5e-20, 1.77e-20, 2.11e-20, 2.35e-20, 2.56e-20, 2.92e-20, 3.07e-20, 3.17e-20, 3.24e-20, 3.26e-20, 3.25e-20, 3.24e-20, 3.23e-20, 3.18e-20, 3.13e-20, 3.02e-20, 2.8e-20, 2.4e-20, 2.15e-20, 1.93e-20, 1.73e-20, 1.6e-20, 1.47e-20, 1.4e-20, 0.0] + threshold: 13.7 + kind: ionization + +- name: hayashi_CH4_elastic_CH4_0.0 + target: CH4 + product: CH4 + energy-levels: [0.0, 0.01, 0.01208, 0.01409, 0.01702, 0.02098, 0.02644, 0.03484, 0.04166, 0.05135, 0.06064, 0.07148, 0.0834, 0.09851, 0.11494, 0.13882, 0.16198, 0.19326, 0.22052, 0.24358, 0.27235, 0.30762, 0.351, 0.40051, 0.46259, 0.53975, 0.62978, 0.74383, 0.92803, 1.10727, 1.36474, 1.70269, 2.12433, 2.39946, 2.83399, 3.38135, 4.03444, 5.19964, 6.34399, 8.36083, 10.30497, 13.44393, 18.33999, 23.35073, 29.49006, 37.54714, 45.81062, 57.15473, 70.58796, 87.88912, 110.9968, 146.2842, 180.2994, 224.9471, 283.5137, 369.8738, 455.88, 543.93, 656.9384, 742.0208, 827.9771, 905.3268, 956.3272] + cross-sections: [2.06383e-19, 2.06383e-19, 1.86094e-19, 1.65686e-19, 1.39635e-19, 1.14736e-19, 9.4276e-20, 7.68131e-20, 6.52849e-20, 5.13162e-20, 4.31565e-20, 3.39225e-20, 2.63285e-20, 2.06952e-20, 1.68262e-20, 1.35368e-20, 1.13843e-20, 9.59438e-21, 8.45252e-21, 7.3528e-21, 6.56032e-21, 6.19671e-21, 6.19671e-21, 6.62996e-21, 7.44656e-21, 9.37407e-21, 1.18005e-20, 1.53655e-20, 2.06952e-20, 2.66643e-20, 3.6371e-20, 5.13162e-20, 7.41042e-20, 9.01863e-20, 1.13531e-19, 1.36429e-19, 1.51303e-19, 1.60181e-19, 1.60181e-19, 1.51303e-19, 1.36429e-19, 1.14736e-19, 8.70058e-20, 6.83897e-20, 5.25223e-20, 3.89139e-20, 3.02664e-20, 2.29515e-20, 1.76264e-20, 1.36805e-20, 1.05064e-20, 7.70248e-21, 6.2625e-21, 5.03823e-21, 4.00227e-21, 3.10631e-21, 2.49906e-21, 2.05342e-21, 1.66953e-21, 1.45539e-21, 1.26871e-21, 1.14399e-21, 1.05577e-21] + threshold: 0.0 + kind: elastic + +- name: hayashi_CH4_dissociation_CH3+H_7.9 + target: CH4 + product: CH3+H + energy-levels: [7.9, 7.90821, 8.08679, 8.1859, 8.26942, 8.37076, 8.45616, 8.54244, 8.73535, 8.8424, 8.93262, 9.13434, 9.34062, 9.55155, 9.76726, 9.98783, 10.19267, 10.55058, 11.03248, 11.39673, 11.91728, 12.43633, 13.00437, 13.90544, 15.02064, 16.06142, 16.76097, 18.32707, 20.45048, 22.8663, 27.28362, 32.8864, 38.84312, 43.87476, 52.8846, 74.53031, 95.08989, 113.4594, 134.0103, 163.5094, 188.4777, 217.7004, 257.1325, 286.9245, 324.092, 386.7002, 451.2133, 521.1721, 615.5719, 695.3117, 801.488, 885.318, 968.0396] + cross-sections: [0.0, 1.06974e-22, 1.28491e-22, 1.61659e-22, 2.47406e-22, 2.93439e-22, 3.48771e-22, 5.03192e-22, 5.90564e-22, 7.25985e-22, 8.9246e-22, 1.07198e-21, 1.34868e-21, 1.65795e-21, 2.05971e-21, 2.50549e-21, 3.08002e-21, 3.73874e-21, 4.87533e-21, 6.19874e-21, 8.25526e-21, 1.06297e-20, 1.30396e-20, 1.46415e-20, 1.64055e-20, 1.79989e-20, 1.99562e-20, 2.31758e-20, 2.59681e-20, 2.7488e-20, 2.84902e-20, 2.72e-20, 2.51074e-20, 2.36692e-20, 2.09028e-20, 1.60297e-20, 1.35151e-20, 1.20365e-20, 1.03862e-20, 8.94329e-21, 7.96484e-21, 7.27505e-21, 6.34406e-21, 5.78244e-21, 5.21532e-21, 4.54791e-21, 4.00791e-21, 3.49501e-21, 3.08002e-21, 2.77794e-21, 2.50549e-21, 2.33723e-21, 2.208e-21] + threshold: 7.9 + kind: excitation + +- name: hayashi_CH4_ionization_CH4^+_12.9 + target: CH4 + product: CH4^+ + energy-levels: [12.9, 13.19695, 13.33182, 13.4955, 13.77277, 13.94186, 14.25727, 14.40299, 14.72883, 15.06204, 15.56021, 16.27222, 17.0168, 18.79994, 21.23981, 22.66805, 25.04337, 27.38768, 29.58817, 32.35792, 35.31504, 39.0156, 45.07628, 50.92631, 58.71766, 70.94303, 86.58983, 104.4058, 120.6242, 140.7863, 162.656, 185.6438, 212.3117, 236.9566, 267.709, 295.7614, 330.765, 372.9327, 421.3322, 471.1971, 514.2588, 580.9997, 656.4023, 725.1848, 791.4579, 865.5462, 914.4029, 987.8718] + cross-sections: [0.0, 1.92453e-22, 2.45358e-22, 3.97115e-22, 5.17086e-22, 6.81888e-22, 8.58391e-22, 1.10598e-21, 1.66953e-21, 2.12848e-21, 2.93414e-21, 3.96023e-21, 6.05442e-21, 7.52561e-21, 1.11229e-20, 1.30594e-20, 1.55286e-20, 1.78135e-20, 1.97556e-20, 2.14064e-20, 2.37403e-20, 2.51864e-20, 2.69473e-20, 2.85889e-20, 2.95714e-20, 3.02664e-20, 3.05877e-20, 3.02664e-20, 2.9199e-20, 2.79324e-20, 2.66643e-20, 2.54538e-20, 2.4043e-20, 2.27104e-20, 2.16794e-20, 2.06952e-20, 1.93428e-20, 1.78135e-20, 1.66494e-20, 1.58936e-20, 1.50127e-20, 1.3855e-20, 1.29223e-20, 1.20524e-20, 1.13843e-20, 1.08675e-20, 1.03961e-20, 1.00295e-20] + threshold: 12.9 + kind: ionization + +- name: pavan_CO_effective_CO_0.0 + target: CO + product: CO + energy-levels: [0.0, 0.001, 0.002, 0.003, 0.005, 0.007, 0.0085, 0.01, 0.015, 0.02, 0.03, 0.04, 0.05, 0.07, 0.1, 0.12, 0.15, 0.17, 0.2, 0.25, 0.3, 0.35, 0.4, 0.5, 0.7, 1.0, 1.2, 1.3, 1.5, 1.7, 1.9, 2.1, 2.2, 2.5, 2.8, 3.0, 3.3, 3.6, 4.0, 4.5, 5.0, 6.0, 7.0, 8.0, 10.0, 12.0, 15.0, 17.0, 20.0, 25.0, 30.0, 50.0, 75.0, 100.0, 150.0, 200.0, 300.0, 500.0, 700.0, 1000.0] + cross-sections: [6.0e-19, 4.0e-19, 2.5e-19, 1.77e-19, 1.23e-19, 9.8e-20, 8.6e-20, 7.8e-20, 6.5e-20, 5.9e-20, 5.4e-20, 5.2e-20, 5.4e-20, 6.1e-20, 7.3e-20, 7.7e-20, 8.8e-20, 9.3e-20, 1.0e-19, 1.12e-19, 1.21e-19, 1.3e-19, 1.385e-19, 1.54e-19, 1.65e-19, 1.85e-19, 2.8e-19, 3.7e-19, 4.2e-19, 4.0e-19, 3.2e-19, 2.35e-19, 2.15e-19, 1.75e-19, 1.6e-19, 1.54e-19, 1.46e-19, 1.42e-19, 1.38e-19, 1.33e-19, 1.29e-19, 1.23e-19, 1.18e-19, 1.13e-19, 1.06e-19, 1.04e-19, 1.02e-19, 1.01e-19, 9.8e-20, 9.1e-20, 8.6e-20, 7.1e-20, 6.1e-20, 5.5e-20, 4.9e-20, 4.2e-20, 3.3e-20, 2.44e-20, 1.96e-20, 1.55e-20] + threshold: 0.0 + kind: effective # according to the LXCat Phelps database. Since the energy levels and cross-sections + # correspond it seems that this data was taken from the Phelps database via LXCat but please note that + # this in an inference from Gaétan Bizot (author of the new format of this file) since no info on the CS + # origin for CO was found in the original file. diff --git a/oxygen-plasma-itikawa.yaml b/oxygen-plasma-itikawa.yaml index 5861ea6..f2c93fd 100644 --- a/oxygen-plasma-itikawa.yaml +++ b/oxygen-plasma-itikawa.yaml @@ -23,9 +23,6 @@ phases: - nasa_gas.yaml/species: [O, O2, O2-, O-, O2+] kinetics: gas - reactions: - - reactions: all - - collisions: all transport: Ion state: {T: 300.0, P: 0.01 atm} electron-energy-distribution: @@ -50,7 +47,7 @@ reactions: - equation: O2+ + e => O + O # Kossyi(40) type: two-temperature-plasma rate-constant: {A: 6.0e-5, b: -1.0, Ea-gas: 0.0, Ea-electron: 0.0} -- equation: E + O2 + O2 => O2- + O2 # Kossyi(45) +- equation: e + O2 + O2 => O2- + O2 # Kossyi(45) type: two-temperature-plasma rate-constant: {A: 4.2e-27, b: -1.0, Ea-gas: 600, Ea-electron: 700} - equation: O- + O => O2 + e # Kossyi(68) @@ -72,9 +69,21 @@ reactions: rate-constant: {A: 3.118e-19, b: -2.5, Ea: 0.0} efficiencies: {O2: 1.0, O: 1.0} -collisions: +# Collisions - equation: O2 + e => O- + O type: electron-collision-plasma + collision: itikawa_O2_attachment_O^-+O_0 +- equation: O2 + e => e + e + O2+ + type: electron-collision-plasma + collision: itikawa_O2_ionization_O2+_13.0 +- equation: O2 + e => e + O + O + type: electron-collision-plasma + collision: itikawa_O2_excitation_O_13.5 + +electron-collisions: +- name: itikawa_O2_attachment_O^-+O_0 + target: O2 + product: O^-+O energy-levels: [4.2, 4.3, 4.4, 4.5, 4.6, 4.7, 4.8, 4.9, 5.0, 5.1, 5.2, 5.3, 5.4, 5.5, 5.6, 5.7, 5.8, 5.9, 6.0, 6.1, 6.2, 6.3, 6.5, 6.6, 6.7, 6.8, 6.9, 7.0, 7.1, 7.2, 7.3, 7.4, 7.5, 7.6, 7.7, 7.8, 7.9, 8.0, 8.1, 8.2, 8.3, 8.4, 8.5, @@ -86,11 +95,20 @@ collisions: 8.97e-23, 8.18e-23, 7.39e-23, 6.42e-23, 5.72e-23, 5.01e-23, 4.49e-23, 3.87e-23, 3.34e-23, 2.82e-23, 2.38e-23, 2.02e-23, 1.67e-23, 1.41e-23, 1.23e-23, 1.06e-23, 8.8e-24, 7.04e-24, 7.04e-24, 6.16e-24, 5.28e-24, 4.4e-24, 4.4e-24, 3.52e-24, 3.52e-24] -- equation: O2 + e => e + e + O2+ - type: electron-collision-plasma + kind: attachment + threshold: 4.2 +- name: itikawa_O2_ionization_O2+_13.0 + target: O2 + product: O2+ energy-levels: [13.0, 15.5, 18, 23] cross-sections: [1.17e-22, 7.3e-22, 1.64e-21, 3.66e-21] -- equation: O2 + e => e + O + O - type: electron-collision-plasma + kind: ionization + threshold: 13.0 +- name: itikawa_O2_excitation_O_13.5 + target: O2 + product: O energy-levels: [13.5, 18.5, 21.0, 23.5] cross-sections: [2.2e-21, 5.29e-21, 5.65e-21, 5.25e-21] + kind: excitation # actually it is a dissociation but on the LXCat website, the Itikawa database comments + # say that "Dissociation is assumed to proceed through excitation to states already included". + threshold: 13.5